Synthesis and structural studies of dinuclear carbonyl ruthenium(II) complexes containing pyridine-2,6-diyl-2-acetyl-6-methyl group as an η2(C,N):η1(C)-bridging ligand

Chemistry Letters

Volumn , Issue 9, 1996, Pages 773-774

  Shimizu, Mayumi ^a   Nakamura, Yukio ^a   Tadokoro, Makoto ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0041355697     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.773     Document Type: Article

References (15)

1. K. Higashimura and Y. Nakamura, J. Chem. Soc., Dalton Trans., 1993, 3075.
2. a) Y. Nakamura and N. Shinkawa, Rhodium Ex., 6, 14 (1994).
3. b) N. Shinkawa, A. Sato, J. Shinya, Y. Nakamura, and S. Okeya, Bull. Chem. Soc. Jpn., 68, 183 (1995).
4. D. J. Darensbourg, B. Fontal, S. S. Chojnacki, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 33, 3526 (1994).
5. a) A. J. Deeming, K. I. Hardcastle, and M. Karim, Inorg. Chem., 31, 4792 (1992).
6. b) U. Bodensieck, L. Hoferkamp, H. Stoeckli-Evans, and G. Suss-Fink, J. Chem. Soc., Dalton Trans., 1993, 127.
7. a) P. L. Andreu, J. A. Cabeza, V. Riera, Y. Jeannin, and D. Miguel, J. Chem. Soc., Dalton Trans., 1990, 2201, and references cited therein.
8. b) M. Mintert and W. S. Sheldrick, J. Chem. Soc., Dalton Trans., 1995, 2663.
9. a) A. J. Deeming and M. B. Smith, J. Chem. Soc., Dalton Trans., 1993, 2041.
10. b) A. J. Deeming, S. N. Jayasuriya, A. J. Arce, and Y. De Sanctis, Organometallics, 15, 786 (1996).
11. 2: C, 28.88; H, 2.60; N, 2.40%.
12. 3, Cu-Kα, λ = 1.54178 Å, R = 0.049 and Rw = 0.087, 5134 reflections (I > 3σ(I)). The solvent hexane molecules were located in difference Fourier synthesis, but disorder in the molecule was not resolved for thermal vibrations.
13. 2: C, 55.63; H, 3.67; N, 1.38%.
14. S. J. La Placa and J. A. Ibers, Inorg. Chem., 4, 778 (1965).
15. A. C. Skapski and P. G. H. Troughton, J. Chem. Soc., Chem. Comm., 1968, 1230.