Cationic bis-diphosphaferrocene copper and gold complexes

New Journal of Chemistry

Volumn 27, Issue 8, 2003, Pages 1233-1239

  Sava, Xavier ^a   Melaimi, Mohand ^a   Ricard, Louis ^a   Mathey, Francois ^a   Le Floch, Pascal ^a  

^a LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BISDIPHOSPHAFERROCENE; CARBONYL DERIVATIVE; CHELATE; COPPER; COPPER COMPLEX; FERROCENE DERIVATIVE; GOLD CHLORIDE; GOLD COMPLEX; LIGAND; OCTA N PROPYL DIPHOSPHAFERROCENE; OCTAETHYL DIPHOSPHAFERROCENE; PHOSPHORUS; UNCLASSIFIED DRUG;

ARTICLE; CRYSTALLIZATION; OXIDATION; PRIORITY JOURNAL; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0041326478     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: 10.1039/b301408h     Document Type: Article

References (38)

1. (a) K. B. Dillon, F. Mathey and J. F. Nixon, Phosphorus: The Carbon Copy, Wiley, Chichester, 1998.
2. For a review on the chemistry of phosphinines, see:P. Le Floch, in Phosphorus - Carbon Heterocyclic Chemistry: The Rise of a New Domain, ed. F. Mathey, Pergamon, Oxford, 2001, p. 485.
3. P. Le Floch, L. Ricard and F. Mathey, Bull. Soc. Chim. Fr., 1996, 133, 691.
4. For a review on the chemistry of phosphaferrocenes, see: F. Mathey, New. J. Chem., 1987, 11, 585-605.
5. D. A. Atwood, A. H. Cowley and S. M. Dennis, Inorg. Chem., 1993, 32, 1527-1528.
6. (a) X. Sava, L. Ricard, F. Mathey and P. Le Floch, Organometallics, 2000, 19, 4899-4903;
7. (b) M. Melaimi, F. Mathey and P. Le Floch, J. Organomet. Chem., 2001, 640, 197-199;
8. (c) X. Sava, L. Ricard, F. Mathey and P. Le Floch, Chem. Eur. J., 2001, 7, 3159.
9. X. Sava, M. Melaimi, N. Mézailles, L. Ricard, F. Mathey and P. Le Floch, New. J. Chem., 2002, 26, 1378.
10. M. Shiotsuka and Y. Matsuda, Chem. Lett., 1994, 351.
11. (a) M. C. Gimeno, A. Laguna, C. Sarroca and P. G. Jones, Inorg. Chem., 1993, 32, 5296;
12. (b) O. Crespo, F. Canales, M. C. Gimeno, P. G. Jones and A. Laguna, Organometallics, 1999, 18, 3142.
13. N. Mézailles, L. Ricard, F. Mathey and P. Le Floch, Eur. J. Inorg. Chem., 1999, 2233.
14. For electrochemical oxidation of phospha and diphosphaferrocenes, see:(a) P. Lemoine, M. Gross, P. Braunstein, F. Mathey and B. Deschamps, J. Organomet. Chem., 1985, 295, 189; (b) P. Lemoine, M. Gross, P. Braunstein, F. Mathey, B. Deschamps and J. H. Nelson, Organometallics, 1984, 3, 1303; (c) P. Lemoine, J. Organomet. Chem., 1989, 359, 61; (d) R. Bartsch, S. Datsenko, N. V. Ignatiev, C. Müller, J. F. Nixon and C. J. Pickett, J. Organomet. Chem., 1997, 529, 375.
15. For electrochemical oxidation of phospha and diphosphaferrocenes, see:(a) P. Lemoine, M. Gross, P. Braunstein, F. Mathey and B. Deschamps, J. Organomet. Chem., 1985, 295, 189; (b) P. Lemoine, M. Gross, P. Braunstein, F. Mathey, B. Deschamps and J. H. Nelson, Organometallics, 1984, 3, 1303; (c) P. Lemoine, J. Organomet. Chem., 1989, 359, 61; (d) R. Bartsch, S. Datsenko, N. V. Ignatiev, C. Müller, J. F. Nixon and C. J. Pickett, J. Organomet. Chem., 1997, 529, 375.
16. For electrochemical oxidation of phospha and diphosphaferrocenes, see:(a) P. Lemoine, M. Gross, P. Braunstein, F. Mathey and B. Deschamps, J. Organomet. Chem., 1985, 295, 189; (b) P. Lemoine, M. Gross, P. Braunstein, F. Mathey, B. Deschamps and J. H. Nelson, Organometallics, 1984, 3, 1303; (c) P. Lemoine, J. Organomet. Chem., 1989, 359, 61; (d) R. Bartsch, S. Datsenko, N. V. Ignatiev, C. Müller, J. F. Nixon and C. J. Pickett, J. Organomet. Chem., 1997, 529, 375.
17. For electrochemical oxidation of phospha and diphosphaferrocenes, see:(a) P. Lemoine, M. Gross, P. Braunstein, F. Mathey and B. Deschamps, J. Organomet. Chem., 1985, 295, 189; (b) P. Lemoine, M. Gross, P. Braunstein, F. Mathey, B. Deschamps and J. H. Nelson, Organometallics, 1984, 3, 1303; (c) P. Lemoine, J. Organomet. Chem., 1989, 359, 61; (d) R. Bartsch, S. Datsenko, N. V. Ignatiev, C. Müller, J. F. Nixon and C. J. Pickett, J. Organomet. Chem., 1997, 529, 375.
18. G. Frenking, I. Antes, M. Böhme, S. Dapprich, A. W. Ehlers, V. Jonas, A. neuhaus, M. Otto, R. Stegmann, A. Veldkamp and S. Vyboishchikov, Reviews in Computational Chemistry, eds. K. B. Lipkowitz and D. B. Boyd, VCH Publishers, Inc., New York, 1996, vol. 8, p. 63.
19. (a) For dative bonding in ferrocenes see: D. Seyferth, B. W. Hames, T. G. Rucker, M. Cowie and R. S. Dickson, Organometallics, 1983, 2, 472;
20. (b) S. Akabori, T. Kumagai, T. Shirahige, S. Sato, K. Kawazoe and D. Tamura, Organometallics, 1987, 6, 2105;
21. (c) M. Sato, K. Suzuki and S. Akabori, Chem. Lett., 1987, 2239;
22. (d) M. Cowie and R. Dickson, J. Organomet. Chem., 1987, 326, 269.
23. + complexing group, Σq means that the charges at C, H, P and Fe atoms were summed.
24. (a) S. Dapprich and G. Frenking, CDA 2.1, Marburg, 1995. The program is available on-line:ftp://chemie.uni-marburg.de (/pub/ cda);
25. (b) S. Dapprich and G. Frenking, J. Phys. Chem., 1995, 99, 9352;
26. (c) G. Frenking and N. Fröhlich, Chem. Rev., 2000, 100, 717.
27. For example, in Schrock carbyne complexes a large deviation from zero (0.381 to 0.621) accounts for the covalent nature of the the C-metal bond, see: S. F. Vyboishchikov and G. Frenking, Chem. Eur. J., 1998, 4, 1439.
28. A. J. Lupinetti, V. Jonas, W. Thiel, S. H. Strauss and G. Frenking, Chem. Eur. J., 1999, 5, 2573.
29. G. J. Kubas, Inorg. Synth., 1990, 28, 68.
30. R. Uson and A. Laguna, Organometallic Syntheses, Elsevier Science Publishers B. V., Amsterdam, 1986, vol. 3, p. 324.
31. Gaussian 98, Revision A. Il, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, Jr., R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, P. Salvador, J. J. Dannenberg, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, A. G. Baboul, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, J. L. Andres, C. Gonzalez, M. Head-Gordon, E. S. Replogle and J. A. Pople, Gaussian, Inc., Pittsburgh PA, 2001.
32. (a) D. Becke, Phys. Rev. A, 1988, 38, 3098-3108; (b) J. P. Perdew, Phys. Rev. B, 1986, 33, 8822.
33. (b) J. P. Perdew, Phys. Rev. B, 1986, 33, 8822.
34. J. Hay and W. R. Wadt, J. Chem. Phys., 1985, 82, 299.
35. A. E. Reed, L. A. Curtis and F. Weinhold, Chem. Rev., 1988, 88, 899-926.
36. A. Altomare, M. C. Burla, M. Camalli, G. Cascarano, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, G. Polidori and R. Spagna, SIR97, an integrated package of computer programs for the solution and refinement of crystal structures using single crystal data, 1999.
37. G. M. Sheldrick, SHELXL-97, Universität Göttingen, Göttingen, Germany, 1998.
38. J. Farrugia, ORTEP-3, Department of Chemistry, University of Glasgow, 2000.