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Volumn 62, Issue 16, 1997, Pages 5374-5379

Secondary and Tertiary 2-Methylbutyl Cations. 3. Theoretical Study of Structures and Interconversions of C5H11+ Ions in the Gas Phase

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EID: 0041189014     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo970706k     Document Type: Article
Times cited : (23)

References (37)
  • 27
    • 0000773869 scopus 로고
    • (c) The theory is the generalization of an earlier model of Pelzer, H.; Wigner, E. Z. Phys. Chem. 1932, B15, 445.
    • (1932) Z. Phys. Chem. , vol.B15 , pp. 445
    • Pelzer, H.1    Wigner, E.2
  • 29
    • 33947088922 scopus 로고
    • It was argued that that the methyl hyperconjugation is not a function of the relative orientation of individual C-H bonds and the empty orbital (Hoffmann, R.; Radom, L.; Pople, J. A.; Schleyer, P. v. R.; Hehre, W. J.; Salem, L. J. Am. Chem. Soc. 1972, 94, 6221.) This representation is in agreement with the low rotational barrier calculated for the 2-propyl cation, but does not explain why in the "chiral" 2-propyl cation the properly oriented C-H bonds are much longer than the other methyl C-H bonds (ref 16).
    • (1972) J. Am. Chem. Soc. , vol.94 , pp. 6221
    • Hoffmann, R.1    Radom, L.2    Pople, J.A.3    Schleyer, P.V.R.4    Hehre, W.J.5    Salem, L.6
  • 33
    • 1542582890 scopus 로고
    • Ph.D. Thesis, Princeton University: Princeton
    • (b) Engler, E. M. Ph.D. Thesis, Princeton University: Princeton, 1973.
    • (1973)
    • Engler, E.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.