Synthesis, ESR, magnetic, and electronic spectral studies on manganese(II) complexes of semicarbazone and thiosemicarbazone

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 31, Issue 10, 2001, Pages 1759-1769

  Chandra, Sulekh ^a   Singh, Gajendra ^a   Tyagi, V P ^b   Raizada, Smriti ^b  

^a UNIVERSITY OF DELHI   (India)

^b Mahanand Mission Harijan College   (India)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0040968797     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-100108260     Document Type: Article

References (29)

1. Campbell, M.J.M. Transition Metal Complexes of Thiosemicarbazide and Thiosemicarbazones. Coord. Chem. Rev. 1975, 15, 279.
2. Ali, M.A.; Livingston, S.E. Metal Complexes of Sulphur-Nitrogen Chelating Agents. Coord. Chem. Rev. 1974, 13, 101.
3. (a) Singh, N.K; Srivastava, A. In vitro and In vivo Antitumour Studies of a New Thiosemicarbazide Derivative and its Complexes with 3d-Metal Ions. Trans. Met. Chem. 2000, 25, 133.
4. (b) Scovill, J.P.; Klayman, D.L.; Franchino, C.F. 2-Acetyl Pyridine Thiosemicarbazones, 4-Complexes with Transition Metal as Antimalarial and Antileukemic Agents. J. Med. Chem. 1982, 25, 1261.
5. (c) Bingham, A.G.; Boegge, H.; Mueller, A.; Ainscough, E.W.; Brodie, A.M. Synthetic, Spectroscopic and X-Ray Crystallograghic Studies on Binuclear Copper(II) Complexes with a Tridentate NNS-Bonding 2-Formylpyridine Thiosemicarbazone Ligand. J. Chem. Soc., Dalton Trans. 1987, 493.
6. Padhye, S.; Kauffman, G.F. Transition Metal Complexes of Semicarbazones and Thiosemicarbazones. Coord. Chem. Rev. 1985, 63, 127 and references therein.
7. 4N-Dialkyl-Thiosemicarbazones, Relation to their Spectral, Magnetic, and Biological Properties. Structure and Bonding 1991, 76, 1.
8. 4N-Dipropylthiosemicarbazones. Trans. Met. Chem. 1992, 17, 568.
9. (a) Chandra, S.; Pandeya, K.B.; Singh, R.P. Some Cr(III) Complexes of Cyclohexanone Semicarbazone and Cyclohexanone Thiosemicarbazone. J. Inorg. Nucl. Chem. 1980, 42, 1075.
10. 4N-Substituted Thiosemicarbazones. Trans. Met. Chem. 1994, 19, 195.
11. Akinchan, N.T.; Akinchan, R.; West, D.X.; Yang, Y. Magnetic Measurements and Spectral Studies on Copper(II) Complexes of Semicarbazones Derived from Isatin, Benzoin and 2-Hydroxynaphthaldehyde. Trans. Met. Chem. 1994, 19, 135.
12. Garg, B.S.; Kapur, L. Spectral Characterisation of Bimetallic Complexes of Thiosemicarbazone of Monoacetylferrocene with Copper(II) Halides. Inorg. Chim. Acta 1990, 173, 223.
13. Talwar, S.; Usha, Chandra, S.; Singh, R.; Veeraswamy, P. Synthesis and Structural Studies on Manganese(II) Complexes of Some N-O and N-S Donor Ligands. Syn. React. Inorg. Met-Org. Chem. 1991, 21, 131.
14. Chandra, S.; Usha; Talwar, S.; Singh, R.; Veeraswamy, P. Stereochemical Studies of Cobalt(II) Complexes of Methyl n-Hexyl Ketone Semicarbazone and Thiosemicarbazone. Syn. React. Inorg. Met-Org. Chem. 1991, 21 (4), 653.
15. Mahadevappa, D.S.; Gowde, B.T.; Murthy, A.S.A. Some Thiosemicarbazide Complexes of Pt(II) and Pd(II). Ind. J. Chem. 1976, 14A, 985.
16. Bassett, J.; Denney, R.C.; Jeffery, G.H.; Mendham, J. Vogel's Textbook of Quantitative Inorganic Analysis, ELBS, 1982, 474.
17. Dyer, J.R. Application of Absorption Spectroscopy to Organic Compounds; Prentice Hall of India Private Limited: New Delhi, 1974; 40.
18. Wiles, D.M.; Gingras, B.A; Suprunchuk, T. Synthesis and Properties of Some Dithiosemicarbazones. Can. J. Chem. 1969, 45, 471.
19. Mashima, M. Infrared Absorption Spectra of Biurea, Semicarbazide, 2,5-Dithiobiurea, and Thiosemicarbazide. Bull. Chem. Soc. Japan 1964, 37, 974.
20. Burns, G.R. Metal Complexes of Thiocarbohydrazides. Inorg. Chem. 1968, 7, 277.
21. Beecroft, B.; Campbell, M.J.M.; Grezeskowiak, R. Complexes of Semicarbazones and Thiosemicarbazones with Nickel(II). J. Inorg. Nucl. Chem. 1974, 36, 55.
22. Nakamoto, K. Coordination Compounds Infrared and Raman Spectra of Coordination Compounds; Wiley Interscience: New York, 3rd Ed. 1978; 317.
23. n Ions. Inorganic Electronic Spectroscopy; Elsevier: Amsterdam, 1984; 2nd Ed. 431.
24. Preti, C.; Tosi, G. Coordination Compounds of Manganese(II) with Tetrahydro-1,4-thiazen-3-one and Thiazolidene-2-thione. Aust. J. Chem. 1976, 20, 243.
25. Figgis, B.N. Free Ions in Medium and Weak Crystal Field. In Introduction to Ligand Fields; John Wiley & Sons: New York, 1976; 145.
26. Huheey, J.B. Principles of Structure and Reactivity. Ed. Harper & Row, Inst. Edition, New York, 1972, 363.
27. Jorgenson, C.K. Oxidation Number and Oxidation State; Springer: New York, 1969, 106.
28. Reed, G.; Cohn, M. Electron Paramagnetic Resonance Spectra of Manganese(II)-Protein Complexes, Manganese(II) Conconvalin. J. Biol. Chem. 1970, 245, 622.
29. Levanon, H.; Luz, Z. ESR and NMR of Mn(II) Complexes in Methanol. J. Chem. Phys. 1968, 49, 2031.