Electron-Transfer Reactions in the Marcus Inverted Region. Charge Recombination versus Charge Shift Reactions

Journal of the American Chemical Society

Volumn 111, Issue 5, 1989, Pages 1917-1919

  Gould, Ian R ^a   Moser, Jacques E ^a   Armitage, Bruce ^a   Farid, Samir ^a   Goodman, Joshua L ^b   Herman, Michael S ^b  

^a EASTMAN KODAK COMPANY   (United States)

^b UNIVERSITY OF ROCHESTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0040959905     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00187a077     Document Type: Article

References (7)

1. (a) Closs, G. L.; Miller, J. R. Science 1988, 240, 440. (b) Miller, J. R.; Beitz, J. V.; Huddleston, R. K. J. Am. Chem. Soc. 1984, 106, 5057. (c) Wasielewski, M. R.; Niemczyk, M. P.; Svec, W. A.; Pewitt, E. B. J. Am. Chem. Soc. 1985, 107, 1080. (d) Irvine, M. P.; Harrison, R. J.; Beddard, G. S.; Leighton, P.; Sanders, J. K. M. Chem. Phys. 1986, 104, 315. (e) Ohno, T.; Yoshimura, A.; Mataga, N. J. Phys. Chem. 1986, 90, 3295.
2. (a) Marcus, R. A. J. Chem. Phys. 1956, 24, 966. (b) Marcus, R. A. Discussions Faraday Soc. 1960, 29, 21.
3. (a) Kakitani, T.; Mataga, N. J. Phys. Chem. 1987, 91, 6277. (b) Kakitani, T.; Mataga, N. J. Phys. Chem. 1986, 90, 993. (c) Kakitani, T.; Mataga, N. Chem. Phys. 1985, 93, 381.
4. sep(ta) are obtained from the size of the transient absorbance due to the DMS radical cation, monitored at 530 nm (ref 4a-d).
5. (a) Goodman, J. L.; Peters, K. S. J. Am. Chem. Soc. 1986, 108, 1700. (b) Ci, X.; daSilva, R. S.; Goodman, J. L.; Nicodem, D. E.; Whitten, D. G. J. Am. Chem. Soc., in press. (c) LaVilla, J. A.; Goodman, J. L. Chem. Phys. Lett. 1987, 141, 149.
6. (a) Van Duyne, R. P.; Fischer, S. F. Chem. Phys. 1974, 5, 183. (b) Ulstrup, J.; Jortner, J. J. Chem. Phys. 1975, 63, 4358. (c) Siders, P.; Marcus, R. A. J. Am. Chem. Soc. 1981, 103, 741, 748.
7. Marcus, R. A. J. Phys. Chem., in press.