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Volumn 17, Issue 4, 1998, Pages 599-602

Oxidation state determination of plutonium aquo ions using x-ray absorption spectroscopy

Author keywords

Oxidation state; Plutonium; XANES

Indexed keywords


EID: 0040844801     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(97)00287-8     Document Type: Article
Times cited : (61)

References (26)
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  • 3
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    • G. T. Seaborg Institute
    • G. T. Seaborg Institute;
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    • (e) PNNL Mailstop K2-44;
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    • (f) LANL Mailstop J514.
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    • 0040005117 scopus 로고
    • (Katz, J. J., Seaborg, G. T. and Morss, L. R., eds) Chapman and Hall, London
    • Weigel, F., Katz, J. J. and Seaborg, G. T., The Chemistry of the Actinide Elements; (Katz, J. J., Seaborg, G. T. and Morss, L. R., eds) Vol. 1, 781, Chapman and Hall, London (1986).
    • (1986) The Chemistry of the Actinide Elements , vol.1 , pp. 781
    • Weigel, F.1    Katz, J.J.2    Seaborg, G.T.3
  • 15
    • 0000209133 scopus 로고
    • Hochella, M. F. and White, A. F., Eds; Mineralogical Society of America, Washington, D.C.
    • Brown, G. E., Mineral-Water Interface Geochemistry; Hochella, M. F. and White, A. F., Eds; Vol. 23; 309, Mineralogical Society of America, Washington, D.C. (1990).
    • (1990) Mineral-water Interface Geochemistry , vol.23 , pp. 309
    • Brown, G.E.1
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    • note
    • V, which was 0.008 M.
  • 19
    • 85033876641 scopus 로고    scopus 로고
    • note
    • XANES data were recorded at 295 K at the Stanford Synchrotron Radiation Laboratory (SSRL): unfocused beamline 4-2, Si(220), double-crystal monochromator, 3.0 GeV, 60-100 mA. The XANES region was taken as extending above the Pu edge to 18,120 eV.
  • 20
    • 85033881543 scopus 로고    scopus 로고
    • note
    • 3 edge spectrum normalized by setting the value of a polynomial fit through the pre-edge region to zero and that of a polynomial fit through the EXAFS region to unity at 18,120 eV. The spectra were calibrated by comparison of spectra for Zr foil, where the first inflection point was defined to be 17,999 eV.
  • 21
    • 85033874317 scopus 로고    scopus 로고
    • note
    • 2)), where x is the X-ray energy in eV and the k's are the fit parameters.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.