A molecular ferromagnet with a Curie temperature of 6.2 Kelvin: [Mn(C5(CH3)5)2] +[TCNQ]-

Science

Volumn 249, Issue 4967, 1990, Pages 401-403

  Broderick, W E ^a   Thompson, J A ^a   Day, E P ^b   Hoffman, B M ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

^b UNIVERSITY OF MINNESOTA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0040820126     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.249.4967.401     Document Type: Article

References (45)

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40. 2)] measured between 4 ≤ 2θ ≤ 50 at - 120°C (Mo Kα radiation, λ = 0.71069). Full interstack interactions and other structural details of I will be discussed later [W. E. Broderick, J. A. Thompson, M. Sabat, E. P. Day, B. M. Hoffman, in preparation]. The atomic coordinates for this work are available on request from the Director of the Cambridge Crystallographic Data Centre, University Chemical Laboratory, Lensfield Road, Cambridge, CB2 1EW, England. Requests should be accompanied by the full literature citation for this communication.
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44. -. . . stack arrangement was also observed in this second structure [J. S. Miller et al., J. Phys. Chem. 91, 4344 (1987)].
45. Supported by the Solid State Chemistry Program of the National Science Foundation (grant DMR-8818599) and by the Northwestern University Materials Research Center under the NSF-MRL program (grant DMR-8821571). We thank the research group of L. Que, Jr., for technical assistance.