Highly diastereoselective formation and structural characterization of [2+2] cycloadducts from the phosphenium complexes Cp(OC)2M=P(Ph) (o-Tol) (M = Mo, W) and isocyanates 1

Inorganica Chimica Acta

Volumn 244, Issue 2, 1996, Pages 147-150

  Malisch, Wolfgang ^a   Hahner, Christoph ^a   Grün, Klaus ^a   Reising, Joachim ^a   Goddard, Richard ^b   Krüger, Carl ^b  

^a UNIVERSITY OF WÜRZBURG   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

Crystal structures; Cycloaddition; Isocyanate complexes; Molybdenum complexes; Phosphametallacycle complexes; Phosphenium complexes; Tungsten complexes

Indexed keywords

CRYSTAL STRUCTURE; CYCLOADDITION; STEREOSELECTIVITY; TUNGSTEN COMPOUNDS;

ISOCYANATE COMPLEXES; MOLYBDENUM COMPLEX; PHOSPHAMETALLACYCLE COMPLEXES; PHOSPHENIUM COMPLEXES; TUNGSTEN COMPLEX;

MOLYBDENUM COMPOUNDS;

EID: 0040793885     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/0020-1693(95)04833-2     Document Type: Article

References (8)

1. W. Malisch, C. Hahner, K. Grün, J. Reising and O. Fey, Chem. Ber., submitted for publication.
2. W. Malisch, M. Märkl, S. Amann, U. Hirth and M. Schmeuβer, Phosphorus Sulfur, 49/50 (1990) 441.
3. A. Spörl, K. Hindahl, A. Fried, H. Pfister and W. Malisch, in H. Werner, A.G. Griesbeck, W. Adam, G. Bringmann and W. Kiefer (eds.), Selective Reactions of Metal-Activated Molecules, Vieweg, Braunschweig, Germany, 1992, p. 195.
4. P. Coppens, L. Leiserowitz and D. Rabinovich, Acta Crystallogr., 18 (1965) 1035; G.M. Sheldrick, Acta Crystallogr., Sect. A, 46 (1990) 468; W.R. Busing, K.O. Martin and H.A. Levy, Rep. ORNL-TM-305, Oak Ridge National Laboratory, Oak Ridge, TN, USA, 1962.
5. P. Coppens, L. Leiserowitz and D. Rabinovich, Acta Crystallogr., 18 (1965) 1035; G.M. Sheldrick, Acta Crystallogr., Sect. A, 46 (1990) 468; W.R. Busing, K.O. Martin and H.A. Levy, Rep. ORNL-TM-305, Oak Ridge National Laboratory, Oak Ridge, TN, USA, 1962.
6. P. Coppens, L. Leiserowitz and D. Rabinovich, Acta Crystallogr., 18 (1965) 1035; G.M. Sheldrick, Acta Crystallogr., Sect. A, 46 (1990) 468; W.R. Busing, K.O. Martin and H.A. Levy, Rep. ORNL-TM-305, Oak Ridge National Laboratory, Oak Ridge, TN, USA, 1962.
7. C.K. Johnson, Rep. ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, USA, 1976.
8. International Tables for X-Ray Crystallography, Vol. C, Kluwer, Dordrecht, Netherlands, 1992, Tables 4.2.6.8 and 6.1.1.4.