Structural and electronic properties of six-coordinate Lewis-base adducts of iron(III) Schiff-base complexes. Crystal structure and magnetism of the high-spin complex [(imidazole)Fe(salen)(NCS)]-0·5 MeOH and of a related complex containing two dissimilar axial ligands

Proceedings of the Indian Academy of Sciences - Chemical Sciences

Volumn 98, Issue 1-2, 1987, Pages 99-114

  Kennedy, Brendan J ^a   Murray, Keith S ^a   Zwack, Peter R ^a   Horn, Ernst ^b   Snow, Michael R ^b   Tiekink, Edward R T ^b  

^a MONASH UNIVERSITY   (Australia)

^b UNIVERSITY OF ADELAIDE   (Australia)

Author keywords

(imidazole)Fe(salen)(NCS); high spin complex; iron(III) Schiff base complexes; magnetism; Mossbauer spectra; Six coordinate Lewis base adducts

Indexed keywords

EID: 0040619201     PISSN: 03700089     EISSN: 09737103     Source Type: Journal    
DOI: 10.1007/BF02886284     Document Type: Article

References (43)

1. A Local View in Magnetochemistry
2. Thiohydroxamato complexes of iron(III). Synthesis, magnetism and Mössbauer spectra
3. Synthesis and Magnetic Properties of Iron(III) Complexes with Several Quadridentate Schiff Bases
4. The electronic state of iron in some natural iron compounds: Determination by Mössbauer and ESR spectroscoopy
5. Preparation and molecular stereochemistry of six-coordinate (isothiocyanato)(pyridine)(porphinato)iron(III) complexes. (Isothiocyanato)(meso-tetraphenylporphinato)(pyridine)iron(III), a low-spin complex with a nonlinear FeNCS group, and (isothiocyanato)(octaethylporphinato)(pyridine)iron(III), a high-spin complex with nonequivalent axial ligands