Reactions of W2(H)(OR)7, W2(OR)6(py)2 and W4(OCH2cC4H7) 12 compounds (R = Pri, CH2But, cC5H9) with azobenzene, 1,2-diphenylhydrazine and 1,1-dimethylhydrazine

Polyhedron

Volumn 16, Issue 12, 1997, Pages 2113-2133

  Barry, Jane T ^a   Chisholm, Malcolm H ^a   Folting, Kirsten ^a   Huffman, John C ^a   Streib, William E ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

Alkoxide; Hydrazido: N N bond; Imido; Tungsten

Indexed keywords

EID: 0040514522     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(96)00490-1     Document Type: Article

References (100)

1. 2 activation at a transition metal center, see: (a) J. Chatt, J. R. Dilworth and R. L. Richards, Chem. Rer. 1978, 78, 589;
2. (b) R. A. Henderson, G. J. Leigh and C. J. Pickett, Adv. Inorg. Chem. Radiochem. 1983, 27, 197;
3. (c) G. J. Leigh, J. Mol. Catal. 1988, 47, 363;
4. (d) G. J. Leigh, Acc. Chem. Res. 1992, 25, 177.
5. Current structural reports on the nitrogenase enzyme include: (a) J. S. Kim and D. C. Rees, Science, 1992, 257, 1677;
6. (b) J. S. Kim and D. C. Rees, Nature. 1992, 553;
7. (c) M. S. Madden, A. M. Krezel, R. M. Allen, P. W. Ludden and V. K. Shah, Proc. Natl. Acad. Sci. 1992, 89, 6487;
8. (d) W. H. Ormejohnson, Science, 1992, 257, 1639;
9. (e) M. M. Georgiadis, H. Komiya, P. Chakrabarti, D. Woo, J. J. Kornuc and D. C. Rees, Science, 1992, 257, 1653;
10. (f) Molybdenum Enzymes, Cofactors, and Model Systems, ed. E. I. Stiefel, D. Coucouvanis and W. E. Newton, Ch. 11 and 12. American Chemical Society, Washington, D. C., 1993.
11. Hydrazine itself is a substrate for the nitrogenase enzyme under certain conditions: (a) L. C. Davis, Arch. Biochem. Biophys. 1980, 204, 270;
12. (b) W. E. Newton, W. A. Bulen, K. L. Hadfield, E. I. Steifel and G. D. Watt, in Recent Developments in Dinitroyen Fixation, ed. W. E. Newton, J. R. Postgate and C. Rodriguez-Barruenco. Academic Press, New York, 1977, p. 119;
13. (c) W. A. Bulen, Proc. Int. Symp. Nitrogen Fixation. 1st, 1976, 177.
14. For a recent review on nitrogenase enzymes, see: B. K. Burgess, Chem. Rev. 1990, 90, 1377.
15. Fe - Mo: (a) T. R. Hawkes, P. A. McLean and B. E. Smith, Biochem. J. 1984, 217, 317;
16. (b) R. D. Joerger, R. Premakumar and P. E. Bishop, J. Bacteriol. 1986, 168, 673;
17. (c) B. J. Hales and E. E. Case, J. Biol. Chem. 1987, 262, 16205;
18. (d) S. D. Conradson, B. K. Burgess, W. E. Newton, L. E. Mortenson and K. O. Hodgson, J. Am. Chem. Soc. 1987, 109, 7507.
19. In the Mo-nitrogenase, hydrazine has been obtained upon quenching of the active enzyme: (a) R. N. F. Thorneley, R. R. Eady and D. J. Lowe, Nature, 1978, 272, 557;
20. (b) R. N. F. Thorneley and D. J. Lowe, Biochem. J. 1984, 224, 887.
21. V - Fe: (a) J. E. Morningstar and B. J. Hales, J. Am. Chem. Soc. 1987, 109, 6854;
22. (b) R. R. Eady, R. L. Robson, T. H. Richardson, R. W. Miller and M. Hawkins, Biochem. J. 1987, 244, 197.
23. For an excellent review of complexes involving dinitrogen containing ligands, see: D. Sutton, Chem. Rev. 1993, 93, 995.
24. (a) R. R. Schrock, A. H. Wesolek, K. C. Wallace and J. C. Dewan, Inorg. Chem. 1988, 27, 2050;
25. (b) M. D. Fryzuk, T. S. Haddad and S. J. Rettig, J. Am. Chem. Soc. 1990, 112, 8185.
26. (a) J. A. Baumann, G. E. Bossard, T. A. George, D. B. Howell, L. M. Koczon, R. K. Lester and C. M. Noddings, Inorg. Chem. 1985, 24, 3568;
27. (b) R. A. Henderson, G. J. Leigh and C. J. Pickett, J. Chem. Soc., Dalton Trans. 1989, 425;
28. (c) W. Hussain, G. J. Leigh and C. J. Pickett, J. Chem. Soc., Chem. Commun. 1982, 747;
29. (d) T. A. George and R. C. Tisdale, Inorg. Chem. 1988, 27, 2909;
30. (e) T. Takahashi, Y. Mizobe, M. Sato, Y. Uchida and M. Hidai, J. Am. Chem. Soc. 1980, 102, 7461;
31. (f) N. J. Lazarowych, R. H. Morris and J. M. Ressner, Inorg. Chem. 1986, 25, 3926.
32. (a) R. A. Henderson, J. Chem. Soc., Dalton Trans. 1982, 917;
33. (b) T. A. George, L. Ma, S. N. Shaikh, R. C. Tisdale and J. Zubieta, Inorg. Chem. 1990, 29, 4789;
34. (c) T. A. George and R. C. Tisdale, Polyhedron, 1989, 8, 1756;
35. (d) T. A. George, L. M. Koczon, R. C. Tisdale, K. Gebreyes, L. Ma, S. N. Shaikh and J. Zubieta, Polyhedron, 1990, 9, 545;
36. (e) Chatt, J., A. J. Pearman and R. J. Richards, J. Chem. Soc., Dalton Trans. 1978, 1766:
37. (f) S. N. Anderson, M. E. Fakley, R. L. Richards and J. Chatt, J. Chem. Soc., Dalton Trans. 1981, 1973.
38. (a) C. R. Dickson and A. J. Nozik, J. Am. Chem. Soc. 1978, 100, 8007;
39. (b) M. Y. Antipin, L. P. Didenko, L. M. Kachapina, A. E. Shilov, A. K. Shilova and Y. T. Struchkov, J. Chem. Soc., Chem. Commun. 1989, 1467:
40. (c) J. O. Dziegielewski and R. Grzybek, Polyhedron, 1990, 9, 645;
41. (d) A. E. Shilov, J. Mol. Catal. 1987, 41, 221:
42. (e) J. Talarmin, T. I. Alsalih, C. J. Pickett, G. E. Bossard, T. A. George and C. M. Duffspence, J. Chem. Soc., Dalton Trans. 1992, 2263.
43. (a) R. R. Schrock, T. E. Glassman, M. G. Vale and M. Kol, J. Am. Chem. Soc. 1993, 115, 1760;
44. (b) R. R. Schrock, A. H. Liu, M. B. O'Regan, W. C. Finch and J. F. Payack, Inorg. Chem. 1988, 27, 3574;
45. (c) R. R. Schrock, T. E. Glassman and M. G. Vale, J. Am. Chem. Soc. 1991, 113, 725;
46. (d) T. E. Glassman, M. G. Vale and R. R. Schrock, Organometallics, 1991, 10, 4046;
47. (e) T. E. Glassman, M. G. Vale and R. R. Schrock, Inorg. Chem. 1992, 31, 1985.
48. M. B. O'Regan, A. H. Liu, W. C. Finch, R. R. Schrock and W. M. Davis, J. Am. Chem. Soc. 1990, 112, 4331.
49. (a) R. R. Schrock, M. E. Listemann and L. G. Sturgeoff, J. Am. Chem. Soc. 1982, 104, 4291;
50. (b) M. E. Listemann and R. R. Schrock, Organometallics, 1985, 4, 74;
51. (c) M. H. Chisholm, D. M. Hoffman and J. C. Huffman, Chem. Soc. Rev. 1985, 69.
52. (a) J. H. Wengrovis, J. Sancho and R. R. Schrock, J. Am. Chem. Soc. 1981, 103, 3932;
53. (b) J. Sancho and R. R. Schrock, J. Mol. Catal. 1982, 15, 75.
54. (a) M. H. Chisholm, C. E. Hammond, J. C. Huffman and V. J. Johnston, J. Organomet. Chem. 1990, 394, C16;
55. (b) M. H. Chisholm, C. E. Hammond, V. J. Johnston, W. E. Streib and J. C. Huffman, J. Am. Chem. Soc. 1992, 114, 7056;
56. (c) R. L. Miller, P. T. Wolczanski and A. L. Rheingold, J. Am. Chem. Soc. 1993, 115, 10422.
57. M. H. Chisholm, V. J. Johnston and W. E. Streib, Inorg. Chem. 1992, 31, 4081.
58. M. H. Chisholm, K. Folting, J. C. Huffman, J. Leonelli, N. S. Marchant, C. A. Smith and L. C. E. Taylor, J. Am. Chem. Soc. 1985, 107, 3722.
59. J. T. Barry, S. T. Chacon, M. H. Chisholm, J. C. Huffman and W. E. Streib, J. Am. Chem. Soc. 1995, 117, 1974.
60. (a) L. S. Hegedus and A. Kramer, Organometallics, 1984, 3, 1263;
61. (b) F. A. Cotton, S. A. Duraj and W. J. Roth, J. Am. Chem. Soc. 1984, 106, 4749.
62. (a) B. Hansert and H. Vahrenkamp, Chem. Ber. 1993, 126, 2017;
63. (b) B. Hansert and H. Vahrenkamp, Chem. Ber. 1993, 126, 2023;
64. H. Vahrenkamp, Pure Appl. Chem. 1989, 61, 1777;
65. E. J. Wucherer, M. Tasi, B. Hansert, A. K. Powell, A. T. Garland, J. F. Halet, J. T. Saillard and H. Vahrenkamp, Inorg. Chem. 1989, 28, 3564.
66. M. H. Chisholm, B. K. Conroy, J. C. Huffman and N. S. Marchant, Angew. Chem., Int. Edn Engl. 1986, 25, 446.
67. L. Blum, I. D. Williams and R. R. Schrock, J. Am. Chem. Soc. 1984, 106, 8316.
68. (a) A. J. Nielson and J. M. Waters, Polyhedron, 1982, 6, 561;
69. (b) A. J. Nielson, J. M. Waters and D. C. Bradley, Polyhedron, 1985, 4, 285.
70. W. Clegg, R. J. Errington and C. Redshaw, J. Chem. Soc., Datlon Trans. 1992, 3189.
71. P. A. Bates, A. J. Nielson and J. M. Waters, Polyhedron, 1987, 6, 163.
72. F. A. Cotton and E. S. Shamshoum, J. Am. Chem. Soc. 1984, 106, 3222.
73. W. A. Nugent and B. L. Haymore, Coord. Chem. Rev. 1980, 31, 123.
74. (a) A. J. Nielson and J. M. Waters, Aust. J. Chem. 1983, 36, 243;
75. (b) D. C. Bradley, M. B. Hursthouse, K. M. A. Malik and A. J. Nielson, J. Chem. Soc., Chem. Commun. 1981, 103.
76. M. G. B. Drew, K. C. Moss and N. Rolfe, Inorg. Nuel. Chem. Lett. 1971, 7, 1219.
77. (a) F. A. Cotton, T. R. Felthouse and D. G. Lay, Inorg. Chem. 1981, 20, 2219;
78. (b) M. H. Chisholm, J. C. Huffman and J. Leonelli, J. Chem. Soc., Chem. Commun. 1981, 270.
79. (a) M. H. Chisholm, D. L. Clark, M. J. Hampden-Smith and D. M. Hoffman, Anqew. Chem., Int. Edn Engl. 1989, 28, 432;
80. (b) M. H. Chisholm, D. M. Hoffman and J. C. Huffman, Inorg. Chem. 1985, 24, 796.
81. A. G. Orpen, J. Chem. Soc., Datlon Trans. 1980. 2509.
82. S. F. Pedersen and R. R. Schrock, J. Am. Chem. Soc. 1982, 104, 7483.
83. R. Mason and K. M. Thomas, J. Organomet. Chem. 1975, 96, C43.
84. (a) V. F. Duckworth, P. G. Douglas, R. Mason and B. L. Shaw, J. Chem. Soc., Chem. Commun. 1970, 1083;
85. (b) R. Mason, K. M. Thomas, J. A. Zubieta, P. G. Douglas, A. R. Galbraith and B. L. Shaw, J. Am. Chem. Soc. 1974, 96, 260.
86. (a) D. M. Hoffman, D. Lappas and D. A. Wierda, J. Am. Chem. Soc. 1989, 111, 1531;
87. (b) 1993, 115, 10,538.
88. M. H. Chisholm, J. C. Huffman, K. S. Kramer and W. E. Streib. J. Am. Chem. Soc. 1993, 115, 9866.
89. C. H. Zambrano, P. E. Fanwick and I. P. Rothwell, Organometallics, 1994, 13, 1174.
90. J. Chatt, J. R. Dilwoth and G. J. Leigh, J. Chem. Soc. (A). 1970, 2239.
91. J. M. Canich, F. A. Cotton. L. R. Falvello and S. A. Duraj, Inorg. Chim. Acta, 1988, 143, 185.
92. (a) P. J. Walsh, F. J. Hollander and R. G. Bergman, J. Am. Chem. Soc. 1988, 110, 8729;
93. (b) P. J. Walsh, F. J. Hollander and R. G. Bergman, Organometallics, 1993, 12, 3705.
94. μ-H is known to have a high trans-effect: T. G. Appleton, H. C. Clark and L. E. Manzer, Coord Chem. Rev. 1973, 10, 335.
95. W - O bonds trans to μ-H are generally longer than those trans to W - O: M. Akiyama, M. H. Chisholm, F. A. Cotton, M. W. Extine, D. A. Haitko, J. Leonelli and D. Little, J. Am. Chem. Soc. 1981, 103, 779.
96. C. Bustos, C. Manzur, D. Carrillo, F. Robert and P. Gouzerb, Inorg. Chem. 1994, 33, 1427.
97. (a) M. Akiyama, M. H. Chisholm, F. A. Cotton, M. W. Extine, D. A. Haitko and D. Little, J. Am. Chem. Soc. 1979, 101, 2504, and ref. 45;
98. (b) M. H. Chisholm, Huffman, J. C. and C. A. Smith, J. Am. Chem. Soc. 1986, 108, 222;
99. (c) S. T. Chacon, M. H. Chisholm, K. Folting, M. J. Hampden-Smith and J. C. Huffman, Inorg. Chem. 1991, 30, 3122.
100. M. H. Chisholm, K. Folting, J. C. Huffman and C. C. Kirkpatrick, Inorg. Chem. 1984, 23, 1021.