Mesomorphic Properties of a Metallomesogen Based on a Copper(II) Metal-Chain Structure

Chemistry of Materials

Volumn 10, Issue 4, 1998, Pages 1069-1075

  Park, Lee Y ^a   Rowe, James M ^a  

^a WILLIAMS COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0040392362     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm970799m     Document Type: Article

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32. If this phase is studied upon cooling from a higher temperature phase, it appears to be liquid crystalline. Therefore, it was necessary to prepare the sample by heating to the isotropic phase followed by cooling and annealing at room temperature for two to three weeks before collecting X-ray diffraction data upon heating. Under these conditions, the sample is clearly crystalline in this temperature range (between 110 and 140 °C.)