The repetitive Diels-Alder reaction: A new approach to [60]fullerene main-chain polymers

Tetrahedron

Volumn 52, Issue 14, 1996, Pages 5007-5014

  Gügel, Andreas ^a   Belik, Pavel ^a   Walter, Michael ^a   Kraus, Alexander ^a   Harth, Eva ^a   Wagner, Manfred ^a   Spickermann, Jochen ^a   Müllen, Klaus ^a  

^a MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

FULLERENE DERIVATIVE; POLYCYCLIC HYDROCARBON; POLYMER;

ARTICLE; DRUG ANALYSIS; DRUG SYNTHESIS; GEL PERMEATION CHROMATOGRAPHY; MASS SPECTROMETRY; PRIORITY JOURNAL; REACTION ANALYSIS;

BETULACEAE;

EID: 0040327344     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00108-1     Document Type: Article

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31. Due to interaction of the samples with the stationary phase (polystyrene gel) all [60]fullerene-containing compounds show a retention volume that is too large. Consequently, the molecular weights determined are too small. Therefore, the determination of correct molecular weights requires an internal calibration. This calibration was performed using MALDI-TOF mass spectrometry of the oligomers 8(n). The correction factor applied is 2 - 4.