Kinetics and mechanism of the outer-sphere oxidation of horse-heart cytochrome c by an anionic chromium(v) complex - Kinetic evidence for precursor formation and a late electron-transfer transition state

European Journal of Inorganic Chemistry

Volumn , Issue 10, 1999, Pages 1805-1812

  Körner, Manuela ^a   Van Eldik, Rudi ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Chromium(v); Cytochrome c; Kinetics; Saturation kinetics; Separation of K and k(ET); Volume profile

Indexed keywords

CHROMIUM COMPOUNDS; COBALT COMPOUNDS; ELECTRON TRANSITIONS; RATE CONSTANTS; REDOX REACTIONS; RUTHENIUM COMPOUNDS;

CHROMIUM(V); COMPLEX KINETICS; CYTOCHROME C; KINETIC EVIDENCE; KINETICS AND MECHANISM; OUTER-SPHERE OXIDATION; SATURATION KINETICS; SEPARATION OF K AND K(ET); TRANSITION STATE; VOLUME PROFILE;

KINETICS;

CHROMIUM DERIVATIVE; COBALT COMPLEX; CYTOCHROME C; RUTHENIUM COMPLEX;

ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONCENTRATION RESPONSE; CONTROLLED STUDY; ELECTROCHEMISTRY; ELECTRON TRANSPORT; ENZYME DEGRADATION; HYPERBARISM; NONHUMAN; OXIDATION REDUCTION REACTION; PH; REACTION ANALYSIS; TEMPERATURE SENSITIVITY;

EID: 0040087253     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199910)1999:10<1805::aid-ejic1805>3.0.co;2-3     Document Type: Article

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