-
2
-
-
0029471603
-
-
Reviews: N. C. Norman, N. L. Pickett, Coord. Chem. Rev. 145, 27 (1995); W. Levason, C. A. McAuliffe, Coord. Chem. Rev. 19, 173 (1976).
-
(1995)
Coord. Chem. Rev.
, vol.145
, pp. 27
-
-
Norman, N.C.1
Pickett, N.L.2
-
3
-
-
0001880625
-
-
Reviews: N. C. Norman, N. L. Pickett, Coord. Chem. Rev. 145, 27 (1995); W. Levason, C. A. McAuliffe, Coord. Chem. Rev. 19, 173 (1976).
-
(1976)
Coord. Chem. Rev.
, vol.19
, pp. 173
-
-
Levason, W.1
McAuliffe, C.A.2
-
6
-
-
0040330735
-
-
Dissertation, Universität München
-
S. Lochschmidt, Dissertation, Universität München (1985).
-
(1985)
-
-
Lochschmidt, S.1
-
8
-
-
85102660626
-
-
note
-
- was observed.
-
-
-
-
9
-
-
0039146442
-
-
note
-
As the term "hypervalence" is used here only in a formal sense, no implication as to the exact number of electrons at the hypervalent atom is intended.
-
-
-
-
11
-
-
0001245169
-
-
K. O. Christe, D. A. Dixon, H. P. A. Mercier, J. C. P. Sanders, G. J. Schrobilgen, W. W. Wilson, J. Am. Chem. Soc. 116, 2850 (1994).
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 2850
-
-
Christe, K.O.1
Dixon, D.A.2
Mercier, H.P.A.3
Sanders, J.C.P.4
Schrobilgen, G.J.5
Wilson, W.W.6
-
12
-
-
29544435901
-
-
a) W. S. Sheldrick, A. Schmidpeter, F. Zwaschka, K. B. Dillon, A. W. G. Platt, T. C. Waddington, J. Chem. Soc., Dalton Trans. 1981, 413;
-
J. Chem. Soc., Dalton Trans.
, vol.1981
, pp. 413
-
-
Sheldrick, W.S.1
Schmidpeter, A.2
Zwaschka, F.3
Dillon, K.B.4
Platt, A.W.G.5
Waddington, T.C.6
-
13
-
-
0039738813
-
-
b) W. S. Sheldrick, F. Zwaschka, A. Schmidpeter, Angew. Chem. 91, 1000 (1979); Angew. Chem. Int. Ed. Engl. 18, 935 (1979).
-
(1979)
Angew. Chem.
, vol.91
, pp. 1000
-
-
Sheldrick, W.S.1
Zwaschka, F.2
Schmidpeter, A.3
-
14
-
-
84985561544
-
-
b) W. S. Sheldrick, F. Zwaschka, A. Schmidpeter, Angew. Chem. 91, 1000 (1979); Angew. Chem. Int. Ed. Engl. 18, 935 (1979).
-
(1979)
Angew. Chem. Int. Ed. Engl.
, vol.18
, pp. 935
-
-
-
16
-
-
85102659101
-
-
note
-
3. See ref. [5].
-
-
-
-
17
-
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85102661530
-
-
note
-
3 (Bz" = p-′butylbenzyl) failed to give single crystals.
-
-
-
-
18
-
-
0000659841
-
-
GED: d(P-C) = 1.844(3) Å; ∠(CPC) = 98.8(3)°: B. Beagley, A. R. Medvid, J. Mol. Struct. 38, 229 (1977); X-ray: J. Bruckmann, C. Krüger, Acta Crystallogr. C51, 1155 (1995).
-
(1977)
J. Mol. Struct.
, vol.38
, pp. 229
-
-
Beagley, B.1
Medvid, A.R.2
-
19
-
-
0001164736
-
-
GED: d(P-C) = 1.844(3) Å; ∠(CPC) = 98.8(3)°: B. Beagley, A. R. Medvid, J. Mol. Struct. 38, 229 (1977); X-ray: J. Bruckmann, C. Krüger, Acta Crystallogr. C51, 1155 (1995).
-
(1995)
Acta Crystallogr.
, vol.C51
, pp. 1155
-
-
Bruckmann, J.1
Krüger, C.2
-
20
-
-
0001442978
-
-
N. Burford, T. S. Cameron, D. J. LeBlanc, P. Losier, S. Sereda, G. Wu, Organometallics 16, 4712 (1997); S. E. Johnson, C. B. Knobler, Phosphorus, Sulfur, 115, 227 (1996); M. Gruber, P. G. Jones, R. Schmutzler, Chem. Ber. 123, 1313 (1990); H.-M. Schiebel, R. Schmutzler, D. Schomburg, U. Wermuth, Z. Naturforsch. 38b, 702 (1983); O. Mundt, H. Riffel, G. Becker, A. Simon, Z. Naturforsch. 43b, 952 (1988);
-
(1997)
Organometallics
, vol.16
, pp. 4712
-
-
Burford, N.1
Cameron, T.S.2
LeBlanc, D.J.3
Losier, P.4
Sereda, S.5
Wu, G.6
-
21
-
-
0030490254
-
-
N. Burford, T. S. Cameron, D. J. LeBlanc, P. Losier, S. Sereda, G. Wu, Organometallics 16, 4712 (1997); S. E. Johnson, C. B. Knobler, Phosphorus, Sulfur, 115, 227 (1996); M. Gruber, P. G. Jones, R. Schmutzler, Chem. Ber. 123, 1313 (1990); H.-M. Schiebel, R. Schmutzler, D. Schomburg, U. Wermuth, Z. Naturforsch. 38b, 702 (1983); O. Mundt, H. Riffel, G. Becker, A. Simon, Z. Naturforsch. 43b, 952 (1988);
-
(1996)
Phosphorus, Sulfur
, vol.115
, pp. 227
-
-
Johnson, S.E.1
Knobler, C.B.2
-
22
-
-
0040802511
-
-
N. Burford, T. S. Cameron, D. J. LeBlanc, P. Losier, S. Sereda, G. Wu, Organometallics 16, 4712 (1997); S. E. Johnson, C. B. Knobler, Phosphorus, Sulfur, 115, 227 (1996); M. Gruber, P. G. Jones, R. Schmutzler, Chem. Ber. 123, 1313 (1990); H.-M. Schiebel, R. Schmutzler, D. Schomburg, U. Wermuth, Z. Naturforsch. 38b, 702 (1983); O. Mundt, H. Riffel, G. Becker, A. Simon, Z. Naturforsch. 43b, 952 (1988);
-
(1990)
Chem. Ber.
, vol.123
, pp. 1313
-
-
Gruber, M.1
Jones, P.G.2
Schmutzler, R.3
-
23
-
-
0039738757
-
-
N. Burford, T. S. Cameron, D. J. LeBlanc, P. Losier, S. Sereda, G. Wu, Organometallics 16, 4712 (1997); S. E. Johnson, C. B. Knobler, Phosphorus, Sulfur, 115, 227 (1996); M. Gruber, P. G. Jones, R. Schmutzler, Chem. Ber. 123, 1313 (1990); H.-M. Schiebel, R. Schmutzler, D. Schomburg, U. Wermuth, Z. Naturforsch. 38b, 702 (1983); O. Mundt, H. Riffel, G. Becker, A. Simon, Z. Naturforsch. 43b, 952 (1988);
-
(1983)
Z. Naturforsch.
, vol.38 B
, pp. 702
-
-
Schiebel, H.-M.1
Schmutzler, R.2
Schomburg, D.3
Wermuth, U.4
-
24
-
-
84944301037
-
-
N. Burford, T. S. Cameron, D. J. LeBlanc, P. Losier, S. Sereda, G. Wu, Organometallics 16, 4712 (1997); S. E. Johnson, C. B. Knobler, Phosphorus, Sulfur, 115, 227 (1996); M. Gruber, P. G. Jones, R. Schmutzler, Chem. Ber. 123, 1313 (1990); H.-M. Schiebel, R. Schmutzler, D. Schomburg, U. Wermuth, Z. Naturforsch. 38b, 702 (1983); O. Mundt, H. Riffel, G. Becker, A. Simon, Z. Naturforsch. 43b, 952 (1988);
-
(1988)
Z. Naturforsch.
, vol.43 B
, pp. 952
-
-
Mundt, O.1
Riffel, H.2
Becker, G.3
Simon, A.4
-
29
-
-
0004201016
-
-
Oxford University Press, New York
-
R. J. Gillespie, P. L. A. Popelier, Chemical Bonding and Molecular Geometry, Oxford University Press, New York (2001); R. J. Gillespie, E. A. Robinson, Angew. Chem. 108, 539 (1996); Angew. Chem. Int. Ed. Engl. 35, 495 (1996); R. J. Gillespie, Chem. Soc. Rev. 1992, 59; R. J. Gillespie, I. Hargittai, The VSEPR Model of Molecular Geometry, Allyn and Bacon, Boston (1991).
-
(2001)
Chemical Bonding and Molecular Geometry
-
-
Gillespie, R.J.1
Popelier, P.L.A.2
-
30
-
-
0000506493
-
-
R. J. Gillespie, P. L. A. Popelier, Chemical Bonding and Molecular Geometry, Oxford University Press, New York (2001); R. J. Gillespie, E. A. Robinson, Angew. Chem. 108, 539 (1996); Angew. Chem. Int. Ed. Engl. 35, 495 (1996); R. J. Gillespie, Chem. Soc. Rev. 1992, 59; R. J. Gillespie, I. Hargittai, The VSEPR Model of Molecular Geometry, Allyn and Bacon, Boston (1991).
-
(1996)
Angew. Chem.
, vol.108
, pp. 539
-
-
Gillespie, R.J.1
Robinson, E.A.2
-
31
-
-
33749113333
-
-
R. J. Gillespie, P. L. A. Popelier, Chemical Bonding and Molecular Geometry, Oxford University Press, New York (2001); R. J. Gillespie, E. A. Robinson, Angew. Chem. 108, 539 (1996); Angew. Chem. Int. Ed. Engl. 35, 495 (1996); R. J. Gillespie, Chem. Soc. Rev. 1992, 59; R. J. Gillespie, I. Hargittai, The VSEPR Model of Molecular Geometry, Allyn and Bacon, Boston (1991).
-
(1996)
Angew. Chem. Int. Ed. Engl.
, vol.35
, pp. 495
-
-
-
32
-
-
0039444404
-
-
R. J. Gillespie, P. L. A. Popelier, Chemical Bonding and Molecular Geometry, Oxford University Press, New York (2001); R. J. Gillespie, E. A. Robinson, Angew. Chem. 108, 539 (1996); Angew. Chem. Int. Ed. Engl. 35, 495 (1996); R. J. Gillespie, Chem. Soc. Rev. 1992, 59; R. J. Gillespie, I. Hargittai, The VSEPR Model of Molecular Geometry, Allyn and Bacon, Boston (1991).
-
Chem. Soc. Rev.
, vol.1992
, pp. 59
-
-
Gillespie, R.J.1
-
33
-
-
0003603208
-
-
Allyn and Bacon, Boston
-
R. J. Gillespie, P. L. A. Popelier, Chemical Bonding and Molecular Geometry, Oxford University Press, New York (2001); R. J. Gillespie, E. A. Robinson, Angew. Chem. 108, 539 (1996); Angew. Chem. Int. Ed. Engl. 35, 495 (1996); R. J. Gillespie, Chem. Soc. Rev. 1992, 59; R. J. Gillespie, I. Hargittai, The VSEPR Model of Molecular Geometry, Allyn and Bacon, Boston (1991).
-
(1991)
The VSEPR Model of Molecular Geometry
-
-
Gillespie, R.J.1
Hargittai, I.2
-
35
-
-
0002611169
-
-
N. W. Alcock, Bonding and Structure - Structural Principles in Inorganic and Organic Chemistry, Ellis Horwood, New York (1990), p. 195; N. W. Alcock, Adv. Inorg. Chem. Radiochem. 15, 1 (1972).
-
(1972)
Adv. Inorg. Chem. Radiochem.
, vol.15
, pp. 1
-
-
Alcock, N.W.1
-
36
-
-
0040330734
-
-
note
-
The secondary bonds are expected to form along the vector of the bond to the most electronegative substituent (Br in 1 and 2), and they do so by avoiding the lone pairs of the original geometry (pyramidal without the secondary bonds), which itself may be predicted by the VSEPR rules.
-
-
-
-
37
-
-
0039444402
-
-
3, however (∠(Br-P-Br) = 101.0(4)°; d(P-Br) = 2.220(3) Å; GED): K. Kuchitsu, T. Shibata, A. Yokozeki, C. Matsumura, Inorg. Chem. 10, 2584 (1971); X-ray: R. Enjalbert, J. Galy, Acta Crystallogr. B35, 546 (1979).
-
(1971)
Inorg. Chem.
, vol.10
, pp. 2584
-
-
Kuchitsu, K.1
Shibata, T.2
Yokozeki, A.3
Matsumura, C.4
-
38
-
-
4243936128
-
-
3, however (∠(Br-P-Br) = 101.0(4)°; d(P-Br) = 2.220(3) Å; GED): K. Kuchitsu, T. Shibata, A. Yokozeki, C. Matsumura, Inorg. Chem. 10, 2584 (1971); X-ray: R. Enjalbert, J. Galy, Acta Crystallogr. B35, 546 (1979).
-
(1979)
Acta Crystallogr.
, vol.B35
, pp. 546
-
-
Enjalbert, R.1
Galy, J.2
-
39
-
-
11244346165
-
-
- salts of triphosphane-1,3-di-ium ions, which may be regarded as 2:1 adducts with other counterions, have been described previously: A. Schmidpeter, S. Lochschmidt, K. Karaghiosoff, W. S. Sheldrick, J. Chem. Soc., Chem. Commun. 1985, 1447.
-
J. Chem. Soc., Chem. Commun.
, vol.1985
, pp. 1447
-
-
Schmidpeter, A.1
Lochschmidt, S.2
Karaghiosoff, K.3
Sheldrick, W.S.4
-
40
-
-
0000850263
-
-
J. L. L. Luetkens, A. P. Sattelberger, H. H. Murray, J. D. Basil, J. J. P. Fackler, Inorg. Synth. 28, 305 (1990); W. Wolfsberger, H. Schmidbaur, Synth. React. Inorg. Metalorg. Chem. 4, 149 (1974).
-
(1990)
Inorg. Synth.
, vol.28
, pp. 305
-
-
Luetkens, J.L.L.1
Sattelberger, A.P.2
Murray, H.H.3
Basil, J.D.4
Fackler, J.J.P.5
-
41
-
-
84943876623
-
-
J. L. L. Luetkens, A. P. Sattelberger, H. H. Murray, J. D. Basil, J. J. P. Fackler, Inorg. Synth. 28, 305 (1990); W. Wolfsberger, H. Schmidbaur, Synth. React. Inorg. Metalorg. Chem. 4, 149 (1974).
-
(1974)
Synth. React. Inorg. Metalorg. Chem.
, vol.4
, pp. 149
-
-
Wolfsberger, W.1
Schmidbaur, H.2
-
46
-
-
0003567345
-
-
University of Nijmegen, The Netherlands
-
P. T. Beurskens, G. Admiral, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israël, J. M. M. Smits, The DIRDIF Program System, University of Nijmegen, The Netherlands (1994).
-
(1994)
The DIRDIF Program System
-
-
Beurskens, P.T.1
Admiral, G.2
Beurskens, G.3
Bosman, W.P.4
De Gelder, R.5
Israël, R.6
Smits, J.M.M.7
-
47
-
-
0004150157
-
-
Universität Göttingen, Germany
-
G. M. Sheldrick, SHELXS-86, Program for the Solution of Crystal Structures, Universität Göttingen, Germany (1986). See also: G. M. Sheldrick in G. M. Sheldrick, C. Krüger, R. Goddard (eds.), Crystallographic Computing 3, p. 175, Oxford University Press, Oxford (1985).
-
(1986)
SHELXS-86, Program for the Solution of Crystal Structures
-
-
Sheldrick, G.M.1
-
48
-
-
0001647167
-
-
G. M. Sheldrick, C. Krüger, R. Goddard (eds.), Oxford University Press, Oxford
-
G. M. Sheldrick, SHELXS-86, Program for the Solution of Crystal Structures, Universität Göttingen, Germany (1986). See also: G. M. Sheldrick in G. M. Sheldrick, C. Krüger, R. Goddard (eds.), Crystallographic Computing 3, p. 175, Oxford University Press, Oxford (1985).
-
(1985)
Crystallographic Computing 3
, pp. 175
-
-
Sheldrick, G.M.1
-
50
-
-
0003830607
-
-
Rep. ORNL-6895, Oak Ridge National Laboratory, Oak Ridge, TN, USA; 1996. Windows version: Louis J. Farrugia, University of Glasgow, Glasgow, Scotland, U.K.
-
C. K. Johnson, M. N. Burnett, ORTEP-III (version 1.0.2), Rep. ORNL-6895, Oak Ridge National Laboratory, Oak Ridge, TN, USA; 1996. Windows version: Louis J. Farrugia, University of Glasgow, Glasgow, Scotland, U.K. (1999).
-
(1999)
ORTEP-III (Version 1.0.2)
-
-
Johnson, C.K.1
Burnett, M.N.2
-
51
-
-
0003473687
-
-
Utrecht University Utrecht, The Netherlands
-
A. L. Spek, PLATON, A Multipurpose Crystallographic Tool, Utrecht University Utrecht, The Netherlands (2000). See also: A. L. Spek, Acta Crystallogr. A46, C34 (1990).
-
(2000)
PLATON, a Multipurpose Crystallographic Tool
-
-
Spek, A.L.1
-
52
-
-
0001748025
-
-
A. L. Spek, PLATON, A Multipurpose Crystallographic Tool, Utrecht University Utrecht, The Netherlands (2000). See also: A. L. Spek, Acta Crystallogr. A46, C34 (1990).
-
(1990)
Acta Crystallogr.
, vol.A46
-
-
Spek, A.L.1
|