Hydrothermal synthesis and characterization of mixed-valence hexatungstates: Crystal structures of [(C2H5)4N]3[WVW VI5O19] · 0.5H2O and [H3N(CH2)2NH3]2 [WVWVI5O19] ·

Inorganica Chimica Acta

Volumn 277, Issue 1, 1998, Pages 69-75

  Khan, M Ishaque ^a   Cevik, Sabri ^a   Doedens, Robert J ^b   Chen, Qin ^c   Li, Sichu ^d   O'Connor, Charles J ^d  

^a Illinois Institute of Technology   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c EMORY UNIVERSITY   (United States)

^d UNIVERSITY OF NEW ORLEANS   (United States)

Author keywords

Crystal structures; Hexatungstate clusters; Hydrothermal synthesis

Indexed keywords

CHLORINE COMPOUNDS; CRYSTAL STRUCTURE; CRYSTALS; LEAST SQUARES APPROXIMATIONS; MIXTURES; MOLECULES; MOLYBDENUM OXIDE; SODIUM COMPOUNDS;

ANALOGOUS REACTIONS; HEXATUNGSTATE CLUSTERS; HYDROTHERMAL REACTION; LEAST SQUARES REFINEMENT; ORTHORHOMBIC SPACE GROUPS; STRUCTURAL ELUCIDATION; SYNTHESIS AND CHARACTERIZATIONS; WATER MOLECULE;

HYDROTHERMAL SYNTHESIS;

EID: 0039992464     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)06124-0     Document Type: Article

References (51)

1. M.T. Pope, Heteropoly and Isopoly Oxometalates, Springer, Berlin, 1983.
2. M.T. Pope and A. Müller, Angew. Chem., Int. Ed. Engl., 30 (1991) 34.
3. M.T. Pope and A. Müller (eds.), Polyoxometalates: from Platonic Solids to Anti-Retroviral Activity, Kluwer, Dordrecht, 1994.
4. D. Gatteschi, R. Sessoli, W. Plass, A. Müller, E. Krickemeyer, J. Meyer, D. Solter and P. Adler, Inorg. Chem., 35 (1996) 1926.
5. D. Gatteschi, L. Pardi, A.L. Barra and A. Müller in M.T. Pope and A. Müller (eds.), Polyoxometalates: from Platonic Solids to Anti-Retroviral Activity, Kluwer, Dordrecht, 1994, p. 219.
6. E. Coronado and C.J. Gomez-Garcia, Comm. Inorg. Chem., 17 (1995) 255.
7. A. Müller, R. Rohlfing, J. Doring and M. Penk, Angew. Chem., Int. Ed. Engl., 30 (1991) 588.
8. A. Müller, J. Doring and H. Bogge, J. Chem. Soc., Chem. Commun., (1991) 273.
9. D.B. Brown (ed.), Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology and Biology, Reidel, Dordrecht, 1980.
10. A. Müller, E. Krickemeyer, M. Penk, H.-J. Walberg and H. Bogge, Angew. Chem., Int. Ed. Engl., 26 (1987) 1045.
11. (a) M. Boyer, B. LeMeur and C.R. Hebd. Séances, Acad. Sci., Ser. C, 281 (1975) 59;
12. (b) C. Sanchez, J. Livage, J.P. Launay and M. Fournier, J. Am. Chem. Soc., 105 (1983) 6817;
13. (c) M. Fournier, Inorg. Synth., 27 (1990) 80.
14. I. Lindquist, Ark. Kemi, 5 (1953) 247.
15. T.R. Mohs, G.P.A. Yap, A.L. Rheingold and E.A. Maatta, Inorg. Chem., 34 (1995) 9, and Refs. therein.
16. A. Proust, R. Thouvenot, S.-G. Roh, J.-K. Yoo and P. Gouzerh, Inorg. Chem., 34 (1995) 4106.
17. C.M. Flynn, Jr. and M.T. Pope, Inorg. Chem., 11 (1971) 2524.
18. (a) W.G. Klemperer and W. Schum, J. Am. Chem. Soc., 100 (1978) 4891;
19. (b) C.J. Besecker, W.G. Klemperer, D.J. Maltbie and D.A. Wright, Inorg. Chem., 24 (1985) 1027;
20. (c) Y. Jeannin, J.P. Launay, C. Sanchez, J. Livage and M. Fournier, Nouv. Chim., 4 (1980) 587.
21. C. Sanchez, J. Livage, J.P. Launay, M. Fournier and Y. Jeannin, J. Am. Chem. Soc., 104 (1982) 3194.
22. M. Dabbabi, M. Boyer, J.P. Launay and Y. Jeannin, J. Electroanal. Chem. Interfacial Electrochem., 76 (1977) 153.
23. K. Nishikawa, A. Kobayashi and Y. Sasaki, Bull. Chem. Soc. Jpn., 48 (1975) 889.
24. Y.-J. Lu, R. Lalancette and R.H. Beer, Inorg. Chem., 35 (1996) 2524.
25. (a) V.W. Day, W.G. Klemperer, Science, 228 (1985) 533;
26. (b) W. Klemperer and W. Shum, J. Chem. Soc., Chem. Commun., (1979) 60.
27. (a) V.W. Day, W.G. Klemperer and D.J. Main, Inorg. Chem., 29 (1990) 2345;
28. (b) W.G. Klemperer and D.J. Main, Inorg. Chem., 29 (1990) 2355.
29. (a) S. Triki, L. Ouahab, J. Padiou and D. Grandjean, J. Chem. Soc., Chem. Commun., (1989) 1068;
30. (b) S. Triki, L. Ouahab, J.-F. Halet, O. Pena, J. Padiou, D. Grandjean, C. Garrigou-Lagrange and P. Delhaes, J. Chem. Soc., Chem. Commun., (1992) 1217;
31. (c) S. Triki, L. Ouahab, D. Grandjean and J.M. Fabre, Acta Crystallogr., Sect. C, 47 (1991) 645.
32. (a) M. Boyer, J. Electroanal. Chem., 31 (1971) 441;
33. (b) M. Boyer and P. Souchay, J. Electroanal. Chem., 38 (1972) 169;
34. (c) S.C. Termes and M.T. Pope, Inorg. Chem., 17 (1978) 500.
35. C.J. O'Connor, Prog. Inorg. Chem., 29 (1982) 203.
36. XSCANS Software Users' Guide, Version 2.1, Siemens Industrial Automation Inc., Madison, WI, 1994.
37. (a) G.M. Sheldrick, SHELXTL Version 5.03, Siemens Industrial Automation Inc., Madison, WI, 1994;
38. (b) Siemens Crystallographic Research Systems SHELXTL PC, Siemens Analytical X-ray Instruments Inc., USA, 1990.
39. R.W. Broach, CARESS, Argonne National Laboratory, Argonne, IL, 1978.
40. (a) R.I. Buckley and R.J.H. Clark, Coord. Chem. Rev., 65 (1985) 167;
41. (b) M. Fournier, C. Rocchiccioli-Deltcheff and L.P. Kazansky, Chem. Phys. Lett, 223 (1994) 297.
42. J. Fuchs, W. Freiwald and H. Hartl, Acta Crystallgr., Sect. B, 34 (1978) 1764.
43. (a) M.I. Khan, Q. Chen and J. Zubieta, Inorg. Chem., 31 (1992) 1556;
44. (b) Q. Chen, D.P. Goshorn, C.P. Scholes, X. Tan and J. Zubieta, J. Am. Chem. Soc., 114 (1992) 4667;
45. (c) M.I. Khan, Q. Chen, H. Hope, S. Parkin, C.J. O'Connor and J. Zubieta, Inorg. Chem., 32 (1993) 2929.
46. A. Müller, M. Penk, R. Rolfing, E. Krickemeyer and J. Döring, Angew. Chem., Int. Ed. Engl., 29 (1990) 926.
47. (a) N. Casan-Pastor and L.C.W. Baker, J. Am. Chem. Soc., 114 (1992) 10 384, and Refs. therein;
48. (b) G.M. Varga, Jr., E. Papaconstantinou and M.T. Pope, Inorg. Chem., 9 (1970) 662;
49. (c) R.A. Prados and M.T. Pope, Inorg. Chem., 15 (1976) 2547; M. Che, M. Fournier and J.P. Launay, J. Chem. Phys., 71 (1979) 1954.
50. (c) R.A. Prados and M.T. Pope, Inorg. Chem., 15 (1976) 2547; M. Che, M. Fournier and J.P. Launay, J. Chem. Phys., 71 (1979) 1954.
51. R.L. Carlin, Magnetochemistry, Springer, Berlin, 1986.