Complexes of polyaza macrocycles bearing pendent coordinating groups

Coordination Chemistry Reviews

Volumn 104, Issue 2, 1990, Pages 297-343

  Bernhardt, Paul V ^a   Lawrance, Geoffrey A ^a  

^a UNIVERSITY OF NEWCASTLE   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0039974775     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/0010-8545(90)80045-U     Document Type: Article

References (149)

1. Synthetic, kinetic, and stereochemical studies on the copper(II), nickel(II), and cobalt(III) complexes of 1,4,7,10,13-penta-aza-cyclopentadecane
2. The Chemistry of 1,4,7-Triazacyclononane and Related Tridentate Macrocyclic Compounds
3. The structures and energy minimization analyses of the macrotricyclic cage complex [Co(nosartacn)]3+and its precursor [Co(taetacn)]3+
4. Synthesis and Binding of a Triazamacrocyclic Ligand Bearing Pendant Pyridyl Groups
5. The Preparation of Trivalent Metal Chelates with Some N3O3-Type Ligands
6. On the structure of [Fe([9]aneN3)2]Cl3.5H2O: some caveats
7. Branched cyclononane macrocycles with pentaamine and tetraamine-thioether donors. Preparation and base hydrolysis of chlorocobalt(III) complexes
8. Metal complexes with macrocyclic ligands. Part XXV. One-step synthesis of mono-N-substituted azamacrocycles with a carboxylic group in the side-chain and their complexes with Cu2+ and Ni2+
9. Metal Complexes with Macrocyclic Ligands. Part XXVIII.. Structures and stabilities of the Cu2+ complexes with 1,4,7-triazacyclononane-1-acetic acid
10. Synthesis and characterization of cyclam complexes of rhodium(III)
11. MACROCYCLIC TETRAAZA COMPLEXES OF SILVER(II). THE KINETICS AND MECHANISM OF THE OXIDATION OF 2-MERCAPTOPYRIMIDINE
12. Complex Formation with Tetraazacycloalkane-N,N?,N?,N?-tetraacetic Acids as a Function of Ring Size
13. Metal Complexes of Macrocyclic Ligands. XII. A Complexone-like Tetraazamacrocycle
14. Metal complexes of macrocyclic ligands. Part XXIV. Binuclear complexes with tetraazamacrocycle-N,N?,N?,N?-tetraacetic acids
15. Structure of the barium salt of a Cu2+ complex with a tetraaza macrocyclic tetraacetate
16. Rapid oxidative metal insertion into a macrocylic ring from a ?metal-out? position and identification of a stable ?metal-in? isomer of a Ni II ?cyclamtetra-acetate complex
17. Synthesis and X-ray structural characterization of novel binuclear complexes of copper(II), nickel(II), and cobalt(II) with an octadentate ligand, N,N?,N?,N?tetrakis(2-aminoethyl)-1,4,8,11-tetra-azacyclotetradecane
18. Crystal and molecular structure of a novel mixed-spin binuclear nickel(II) complex with N,N?,N?,N?-tetrakis(2-aminoethyl)-1,4,8,11-tetra-azacyclotetradecane
19. Preparation of 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetra-azacyclotetradecane (L1) and a binuclear complex with copper(II). X-Ray structure of [Cu2L1Br2][ClO4]2
20. Co-ordination chemistry of ruthenium with chelating amine ligands: synthesis and X-ray structural study of the N6-co-ordinated ruthenium(II) complex of 1,4,8,11-tetrakis(2-pyridylmethyl)-1,4,8,11-tetra-aza-cyclotetradecane
21. Chemistry of structurally developed macrocycles. Part 1. Complexation properties of NN?N?N?-tetra(2-cyanoethyl)-1,4,8,11-tetra-azacyclotetradecane with nickel(II)
22. Chemistry of structurally developed macrocycles. Part 2. Synthesis and complexing properties of N,N?,N?,N?-tetra(3-aminopropyl)-1,4,8,11-tetra-azacyclotetradecane with nickel(II)
23. Unexpected and facile equilibration of six-co-ordinate bis(solvento)-(R,S,S,R)(1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(II) ions with the five-co-ordinate mono(solvento)-(R,S,R,S)-complexes in some co-ordinating solvents
24. 1,4,7,10-Tetrakis(2-hydroxyethyl)-1,4,7,10-tetra-azacyclododecane: a strong cation complexer
25. Metal complexes of macrocyclic ligands. Part XXIII. Synthesis, properties, and structures of mononuclear complexes with 12- and 14-membered tetraazamacrocycle-N,N?,N?,N?-tetraacetic Acids
26. Crystal and molecular structure of sodium aqua(1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetato)europate(III) tetrahydrate Na+(EuDOTA.H2O)-.4H2O, and its relevance to NMR studies of the conformational behavior of the lanthanide complexes formed by the macrocyclic ligand DOTA
27. N-(aminoethyl)cyclam: a tetraaza macrocycle with a coordinating tail (scorpiand). Acidity controlled coordination of the side chain to nickel(II) and nickel(III) cations
28. A novel cyclam?nickel(II) complex appended with a tris-(2,2?-bipyridine) ruthenium(II) complex (cyclam = 1,4,8,11-tetra-azacyclotetradecane)
29. Metal Complexes with Macrocyclic Ligands. Part XXVII. Cu2+-promoted hydrolysis of carboxylic- and phosphonic-acid esters in the side chain of tetraazamacrocycles
30. Studies of pendant-arm macrocyclic ligands. Part 1. Synthesis of two new penta-aza ligands, and observation of pH-dependent reversible equilibria between trigonal-bipyramidal and square-planar forms of their nickel(II) and copper(II) complexes. Crystal structure of a trigonal-bipyramidal nickel(II) complex
31. Metal complexes with macrocyclic ligands, XVII. Synthesis of two key intermediates for the preparation of mono-N-functionalized tetraazamacrocycles and their metal complexes
32. Studies of pendant-arm macrocyclic ligands. Part 5. Synthesis of two pyridine-containing penta-aza macrocycles with single pyrrolidinyl pendant arms and characterisation of their nickel(II) and copper(II) complexes. Crystal structure of perchlorato{7-[2?-(1?-pyrrolidinyl)ethyl]-3,7,11,17-tetra-azabicyclo[11.3.1]heptadeca-1(17),13,15-triene}nickel(II) perchlorate
33. Studies of pendant-arm macrocyclic ligands. Part 4. Two penta-aza macrocycles based on 1-(2?-dimethylaminoethyl)-1,5,9,13-tetra-azacyclohexadecane and its complexes with bivalent metal ions
34. 6, 13-Diamino-6,13-dimethyl-1,4,8,11-tetra-azacyclotetradecane, L7, a new, potentially sexidentate polyamine ligand. Variable co-ordination to cobalt (III) and crystal structure of the complex[CO(L7)]Cl2[ClO4]
35. Coordination of the "pendant-arm" macrocycle 6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane to chromium(III). Crystal structure and physical properties of the hexacoordinated complex ion
36. Rhodium(III) complexes of the ambidentate macrocycle 6,13-diamino-6,13-dimethyl-1,4,8,11-tetra-azacyclotetradecane. Crystal structure of the sexidentate complex
37. Co-ordination of 6,13-diamino-6,13-dimethyl-1,4,8,11-tetra-azacyclotetradecane to iron(III). The first fully characterised hexa-amineiron(III) complex
38. Hexaco-ordination of a diamino-substituted tetra-azameacrocycle to cobalt(III) and nickel(II): compressed Co?N bonds?
39. Crystal Structure of Hexaamminecobalt(III) Chloride Chromate Trihydrate
40. Etudes structurales des complexes racémiques hydratés (±)-Co(en)3Cl3 et (±)-Cr(en)3C13
41. Reduction potentials of pentaammine complexes of cobalt(III), rhodium(III) and iridium(III): physical correlations
42. Synthesis of a thirteen-membered tetra-azamacrocycle employing formaldehyde and nitroalkanes directed by metal ions. Crystal structures of (12-methyl-12-nitro-1,4,7,10-tetra-azacyclotridecane)copper(II) perchlorate and �-chloro-1,1,1-trichloro-2-(12-methyl-12-nitro-1,4,7,10-tetra-azacyclotridecane)dicopper(II)
43. Metal Directed Synthesis Involving Formaldehyde and Nitroethane, and Crystal Structure of the Copper(II) Complex of the 14-Membered Macrocycle 6-Methyl-6-Nitro-1,4,8,11-Tetraazacyclotetradecane
44. Comparisons of thirteen- to sixteen-membered tetra-azacycloalkane copper(II) complexes derived from template syntheses involving nitroethane and formaldehyde. Crystal structures of (10-methyl-10-nitro-1,4,8,12-tetra-azacyclopentadecane)copper(II) and (3-methyl-3-nitro-1,5,9,13-tetra-azacyclohexadecane)copper(II) perchlorates
45. Reactions of (10-Methyl-10-nitro-1,4,8,12-tetraaza-cyclopentadecane)copper(II) Ion in Aqueous Hydrochloric Acid, Including Zinc Reduction. Crystal-Structure of (2-methyl-1,4,8,11-tetraaza-cyclotetradec-1-ene)copper(II) Perchlorate
46. Condensations of Ethane-1,2-Diamine, Formaldehyde and Ammonia (or Nitroethane) Directed by Nickel(II) or Copper(II). Crystal Structure of (8-Methyl-8-nitro-1,3,6,10,13,15-hexaazatricyclo[13.1.1.113,15]octadecane)nickel(II) Perchlorate
47. NICKEL(II) COMPLEXES OF NOVEL MACROCYCLIC LIGANDS CONTAINING PENDANT NITRO GROUPS
48. Tetraazamacrocyclic Nickel(II) Complexes Containing a Pendant Amino Group
49. Tetra-aza macrocyclic complexes containing a pendant amino group. Copper(II), nickel(II), and cobalt(III) complexes of 5-aminomethyl-2,5,10,12-tetramethyl-1,4,8,1 1-tetra-azacyclotetradecane (L) and X-ray structural characterisation of the cobalt(III) complex [Co(L)Cl][ClO4]Cl�EtOH
50. The formation of a novel quinquedentate N4O ligand by dioxygen oxidation of trans-(RSSR)-[CoCl2(teta)]ClO4
51. A new cyclam providing the first example unequivocally proven by X-ray crystallography of a pendent co-ordinated pyridyl group
52. Novel synthesis and complex properties of macrocylic tetra-amines appended with phenol as an axial donor
53. A new cyclam with an appended imidazole. The first biomimetic ligation of imidazole for axial ?-interaction with metal ions
54. The effects of size and donor atoms of macrocyclic polyamines binding to Mg2+ and Ca2+.
55. Hydroxyethylation of Macrocyclic Polyamines; Inhibition by Partial Protonation.
56. Kinetics of the superoxide radical oxidation of [cobalt sepulchrate](2+) ion. A flash photolytic study
57. Outer-sphere electron-transfer reactions involving caged cobalt ions
58. Chemical and Electrochemical Electron-Transfer Theory
59. Structure of (1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]icosane)platinum(IV) dithionate 2.5 hydrate
60. Macrotricyclic hexaamine cage complexes of cobalt(III): synthesis, characterization and properties
61. Synthesis and characterization of a stable hexa-amine vanadium(IV) cage complex
62. A synthetic route to encapsulated Ru compounds: properties of the [Ru(3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane)]2+/3+ ions
63. Spin equilibria in iron(II) hexa-amine cages
64. ELECTRONIC AND LIGAND STRUCTURE DICTATED EFFECTS FOR TRIGONAL, TETRAGONAL AND RHOMBIC SYMMETRIES OF TRANSITION METAL CAGE COMPLEXES
65. Synthesis of the cage penta-azamacrobicycloalkane 12,1 7-dimethyl-1,5,9,1 2,17-penta-azabicyclo[7.5.5]nonadecane, its basicity, and metal complex formation. Crystal structure of the copper(II) perchlorate complex
66. Small Synthetic Macrocyclic Cages. Proton Transfer Properties and Metal Complexes
67. Synthesis and X-ray crystal structure of a C-spiro-bi-[cyclam nickel(II)] complex (cyclam = 1,4,8,11-tetra-azacyclotetradecane)
68. Characterization of 2,2?-bi-(1,4,8,11-tetra-azacyclotetradecane): X-ray structure and properties of the dinuclear complex [Ni2(C20H46N8)][ClO4]4
69. Bicyclam [6,6?-bi(1,4,8,11-tetra-azacyclotetradecane)]: a ditopic receptor for homo- and hetero-bimetallic complexes
70. Synthesis of 1,2-bis(1,4,7,10-tetra-azadodecanyl)ethane, a double-ring fully saturated macrocycle containing 12-membered tetra-aza subunits
71. EPR Evidence For Magnetic Exchange Through a Four-Carbon Aliphatic Bridge in a Binuclear Copper(II) Complex. Single Crystal X-Ray Structure of 7, 7′-(1, 4-Butanediyl)-Bis{2,12-Dimethyl-3,7,11,17-Tetraazabicyclo[11.3.1]Heptadeca-1(17),2,11,13,15-Pentaene)Nickel(II)} Perchlorate Monohydrate