Synthesis and X-ray crystal structure of the heterobimetallic complex [FeRh(μ-CO)(CO)3μ-PBut2(μ-Ph 2PCH2PPh2)]

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Volumn 52, Issue 7, 1997, Pages 810-814

  Böttcher, Hans Christian ^a   Merzweiler, Kurt ^a   Bruhn, Clemens ^a  

^a MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

Author keywords

Crystal Structure; Dinuclear Iron Rhodium Complex; Homogeneous Catalysis; Hydroformylation; Phosphido Bridged

Indexed keywords

CARBONYLATION; CATALYSIS; CATALYSTS; ETHYLENE; HYDROFORMYLATION; IRON COMPOUNDS; RHODIUM COMPOUNDS;

HETERO BIMETALLIC COMPLEXES; HOMOGENEOUS CATALYSIS; HOMOGENEOUS CATALYST; METAL CARBONYL; PHOSPHIDO; RHODIUM COMPLEXES; SPACE GROUPS; X RAY CRYSTAL STRUCTURES;

CRYSTAL STRUCTURE;

EID: 0039972312     PISSN: 09320776     EISSN: None     Source Type: Journal    
DOI: 10.1515/znb-1997-0708     Document Type: Article

References (17)

1. a) R. J. Puddephatt, Chem. Soc. Rev. 12, 99 (1983);
2. b) B. Chaudret, B. Delavaux, R. Poilblanc, Coord. Chem. Rev. 86, 191 (1988);
3. c) D. F. Shriver, H. D. Kaesz, R. D. Adams (eds): The Chemistry of Metal Cluster Complexes, VCH, New York (1990);
4. d) A. Balch, in L. H. Pignolet (ed): Homogeneous Catalysis with Metal Phosphine Complexes, pp. 167 - 213, Plenum, New York (1983).
5. B. Walther, H.-C. Böttcher, M. Scheer, G. Fischer, D. Fenske, G. Süss-Fink, J. Organomet. Chem. 437, 307 (1992).
6. H. Hartung, A. Krug, H.-C. Böttcher, J. Organomet. Chem. 487, C1 (1995) and references cited therein.
7. L.-K. Liu, L.-S. Luh, Y.-S. Wen, U. B. Eke, M. A. Mesubi, Organometallics 14, 4474 (1995) and references cited therein.
8. M. J. Chetcuti, in G. Wilkinson, F. G. A. Stone, E. W. Abel (eds): Comprehensive Organometallic Chemistry II, Vol. X, pp. 23 - 85, Pergamon Press, Oxford (1995).
9. G. B. Jacobsen, B. L. Shaw, M. Thornton-Pett, J. Chem. Soc. Dalton Trans. 1987, 2751.
10. I. Mansfield, N. Nawar, A. K. Smith, N. C. Tong, J. Organomet. Chem. 525, 255 (1996).
11. H. A. Jenkins, S. J. Loeb, D. W. Stephan, Inorg. Chem. 28, 1998 (1989).
12. A. M. Arif, D. E. Heaton, R. A. Jones, Polyhedron 10, 543 (1991).
13. M. D. Curtis, K. R. Han, W. M. Butler, Inorg. Chem. 19, 2096 (1980).
14. R. H. Crabtree, M. Lavin, Inorg. Chem. 25, 805 (1986).
15. F. A. Cotton, Prog. Inorg. Chem. 21, 1 (1976).
16. Further details of the crystal structure determination are available on request from the Fachinformationszentrum Karlsruhe GmbH, D-76344 Eggenstein-Leopoldshafen, on quoting the depository number CSD-406841.
17. G. M. Sheldrick SHELXS-86, SHELXL-93, Programs for Crystal Structure Determination. University of Göttingen.