Long-lived glycosyl-chromium(III) complex intermediates in aqueous medium. Preparation of pyranoid glycals

Tetrahedron Letters

Volumn 37, Issue 8, 1996, Pages 1293-1296

  Kovács, Gyöngyvér ^a   Gyarmati, Julianna ^a   Somsák, László ^a   Micskei, Károly ^a  

^a UNIVERSITY OF DEBRECEN   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

PYRAN DERIVATIVE;

ARTICLE; CATALYSIS; DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0039730431     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(95)02377-1     Document Type: Article

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34. To the best of our knowledge no direct evidence for the existence of glycosyl-metal intermediates is known in the literature.
35. The evaluation of the kinetic curves under the applied pseudo-first order conditions are complicated. The results of these investigations will be published elsewhere.
36. 4. The solvent was evaporated under diminished pressure to give 7 as a syrup, which crystallized on standing.
37. 4) and after removal of the solvent gave 7.
38. The isolated products had physical and NMR characteristics identical with those of authentic samples.