Organophosphorus compounds; 142:1 A simple approach to 1,2,4-selena-and telluradiphospholes from phosphaalkynes and the chalcogen elements and a first study of their reactivity

Synthesis

Volumn , Issue 9, 1999, Pages 1642-1650

  Asmus, Sven M F ^a   Bergsträßer, Uwe ^a   Regitz, Manfred ^a  

^a Rheinland Pfälzische Technische Universität Kaiserslautern Landau   (Germany)

Author keywords

Cage compounds; Chalcogenes; Diels Alder reaction; Heterophospholes; Phosphaacetylenes

Indexed keywords

BROMINE; CHALCOGEN; ORGANOPHOSPHORUS COMPOUND; SELENIUM; TELLURIUM;

ALKYLATION; ARTICLE; CHEMICAL REACTION; CRYSTAL STRUCTURE; REACTION ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0039646480     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-3573     Document Type: Article

References (22)

1. Part 141, see: Löber, O.; Bergsträßer U.; Regitz, M. Synthesis 1999, 644.
2. (a) Schmidpeter, A.; Karaghiosoff, K. In Multiple Bonds and Low Coordination in Phosphorus Chemistry; Regitz, M.; Scherer, O. J., Eds.; Thieme: Stuttgart, 1990; p 258.
3. (b) Regitz, M. In Multiple Bonds and Low Coordination in Phosphorus Chemistry; Regitz, M.; Scherer, O. J., Eds.; Thieme: Stuttgart 1990; p 58.
4. Bansal, R. K.; Karaghiosoff, K.; Gandhi, N.; Schmidpeter, A. Synthesis 1995, 361.
5. Regitz, M.; Krill S. Phosphorus, Sulfur, and Silicon 1996, 115, 99.
6. Regitz, M. Chem. Rev. 1990, 90, 191.
7. Mack, A.; Regitz M. Chem. Ber. 1997, 130, 823.
8. Caliman, V.; Hitchcock P. B.; Nixon, J. F.; Sakarya, N. Bull. Soc. Chim. Belg. 1996, 105, 675.
9. Appel, R. In Multiple Bonds and Low Coordination in Phosphorus Chemistry; Regitz, M.; Scherer, O. J., Eds.; Thieme: Stuttgart, 1990; p 157.
10. CRC Handbook of Chemistry and Physics, 73rd Ed.; Lide, D. R., Ed.; CRC Press: Boca Raton, 1992, p 9-1.
11. Mathey, F. Chem. Rev. 1990, 90, 997.
12. Julino, M.; Bergsträßer, U.; Regitz M. Synthesis 1992, 87.
13. Main structural features of 11a were proved by an X-ray structure analysis. A discussion of structural details is not possible due to the poor quality of the data set.
14. Niecke, E.; Böske, J.; Krebs, B.; Dartmann, M. Chem. Ber. 1985, 118, 3227.
15. Rösch, W.; Allspach, T.; Bergsträßer, U.; Regitz, M. In Synthetic Methods of Organometallic and Inorganic Chemistry, Vol. 3; Herrmann, W. A., Ed.; Thieme: Stuttgart, 1996, p 11.
16. Sheldrick, G. M., Fortran Program for the Solution of Crystal Structures from Diffraction Data, Institute for Organic Chemistry, University of Göttingen, 1986.
17. Sheldrick, G. M., Fortran Program for Crystal Structure Refinement, Institute for Organic Chemistry, University of Göttingen, 1993.
18. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-11481 (8a) and CCDC-11482 (12). Copies of the data can be obtained free of charge on application to: CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax +44 122 3336033; e-mail: deposit@ccdc.cam.ac.uk).
19. (a) Geißler, B. Ph.D Thesis, University of Kaiserslautern, 1993.
20. (b) Birkel, M. Ph. D. Thesis, University of Kaiserslautern, 1992.
21. (c) Mack. A.; Regitz, M. Chem. Ber. Recueil 1997, 130, 823.
22. Nachbauer A.; Bergsträßer U.; Leininger S.; Regitz M. Synthesis 1998, 427.