Kinetic study on the reaction of cis-[Pd(en)(H2O)2] (NO3)2 and N-AcCysMe

Chinese Science Bulletin

Volumn 41, Issue 5, 1996, Pages 390-394

  Chen, Xiaohua ^a   Zhu, Longgen ^a   Yan, Hong ^a   Kostic, N M ^a,b   You, Xiaozeng ^a  

^a NANJING UNIVERSITY   (China)

^b IOWA STATE UNIVERSITY   (United States)

Author keywords

Cis Pd(en)(H2O)2 (NO3)2; Kinetics; N AcCysMe

Indexed keywords

EID: 0039600713     PISSN: 10016538     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (5)

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2. Chin, J., Developing artificial hydrolytic metalloenzymes by a unified mechanistic approach, Acc. Chem. Res., 1991, 24: 145.
3. Zhu, L., Kostić, N. M., Selective hydrolysis of peptides promoted by Pd aqua complexes: Kinetic effects of the leaving group, pH, and inhibitors, J. Am. Chem. Soc., 1993, 115: 4566.
4. Zhu, L., Kostić, N. M., Toward artificial metallopeptidases: mechanisms of selective, fast hydrolysis of unactivated amide bonds in peptides promoted by Pt(II) and Pd(II) complexes, Inorg. Chem., 1992, 32: 3994.
5. Zhu, L., Qin, L., Parac, T. N. et al., Site-specific hydrolytic cleavage of cytochrome C and of its heme undecapeptide, promoted by coordination complexes of palladium (II), J. Am. Chem. Soc., 1994, 116: 5218.