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-8 s, corresponding to many thousands C-C rotations), may in principle undergo a sort of intramolecular "internal return" yielding again H-I, but with an inverted configuration [V. C. Ukachukwu, J. J. Blumenstein, D. L. Whalen, J. Am. Chem. Soc. 108 (1986) 5039]. In this case, racemization of the starting epoxide would be observable, in contrast to the experimental evidence.
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