Synthesis and axial-ligand binding of zinc complexes of amphiphilic porphyrins containing a hydrophobic binding pocket

Chemistry Letters

Volumn , Issue 8, 1997, Pages 819-820

  Imai, Hiroyasu ^a   Munakata, Hiroki ^a   Takahashi, Atsuko ^a   Nakagawa, Shigeo ^a   Uemori, Yoshio ^a  

^a HOKURIKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0039504566     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.819     Document Type: Article

References (21)

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16. 3; pH 11.5), and this prevents pH changes upon amine titration.
17. Complex Zn2 is soluble in water, alcohols, and acetone, but not in chloroform to allow spectral measurements.
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21. In general, polar binding such as coordination is stronger in non-polar solvents than in aqueous solution. However, this is not the case for Zn1, probably due to the hydrophobic interaction in aqueous solution.