Role of the intramolecular hydrogen bond and ligand rigidity in the complexation of trifluoroacetylcycloalkanones with lanthanides: Novel strategy for the design of organic ligands of high selectivity

Inorganica Chimica Acta

Volumn 267, Issue 2, 1998, Pages 201-207

  Umetani, Shigeo ^a   Kawase, Yusuke ^a   Le, Quyen T H ^a   Matsui, Masakazu ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Intramolecular hydrogen bond; Lanthanide complexes; Ligand rigidity; Molecular design; O O distances; Solvent extraction; diketone complexes

Indexed keywords

CALCULATIONS; COMPLEXATION; DISSOCIATION; KETONES; LIGANDS; RARE EARTH ELEMENTS; RIGIDITY; SOLVENT EXTRACTION; TITRATION; VOLTAMMETRY;

AB INITIO CALCULATIONS; ACID DISSOCIATION CONSTANTS; DIKETONES; INTRA-MOLECULAR HYDROGEN BONDS; LANTHANIDE COMPLEX; MOLECULAR DESIGN; POTENTIOMETRIC TITRATIONS; SOLVENT-EXTRACTION TECHNIQUES;

HYDROGEN BONDS;

EID: 0039401858     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(97)05613-2     Document Type: Article

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