The First Mixed-Halide Zirconium Cluster Compounds: Zr6Cl1.6I10.4Be, Zr6Cl1.3I10.7B, and Zr6Cl11.5I1.5B. Matrix Effects and Halogen Substitution in Compact Network Structures

Inorganic Chemistry

Volumn 35, Issue 6, 1996, Pages 1437-1443

  Köckerling, Martin ^a   Qi, Ru Yi ^a   Corbett, John D ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0039367301     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950889y     Document Type: Article

References (29)

1. Ziebarth, R. P.; Corbett, J. D Acc. Chem. Res. 1989, 22, 256.
2. (a) Corbett, J. D. In Modern Perspectives in Inorganic Crystal Chemistry; Parthé, E., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; p 27.
3. (b) Corbett, J. D. J. Alloys Compd. 1995, 229, 10.
4. 2-: Zhang, J.; Corbett, J. D. Inorg. Chem. 1995, 34, 1652.
5. Smith, J. D.; Corbett, J. D. J. Am. Chem. Soc. 1985, 107, 5704.
6. Smith, J. D.; Corbett, J. D. J. Am. Chem. Soc. 1986, 108, 1927.
7. Simon, A.; von Schnering, H.-G.; Wöhrle, H.; Schäfer, H. Z Anorg. Allg. Chem. 1965, 339, 155.
8. Qi, R.-Y.; Corbett, J. D. Inorg. Chem. 1995, 34, 1646.
9. Qi, R.-Y. Ph.D. Dissertation, Iowa State University, 1993.
10. Sägebarth, M.; Simon, A. Z. Anorg. Allg. Chem. 1990, 587, 119.
11. Yoshiasa, A.; Borrmann, H.; Simon, A. Z. Anorg. Allg. Chem. 1994, 620, 1329.
12. Daake, R. L ; Corbett, J. D. Inorg. Synth. 1983, 22, 26.
13. Guthrie, D. H.; Corbett, J. D. J. Solid State Chem. 1981, 37, 256.
14. Preliminary structural results indicate that this phase contains Zr octahedra condensed in one lattice direction and fewer than 12 halides per octahedron: Köckerling, M.; Qi, R.-Y.; Corbett, J. D. Unpublished.
15. Data reduction was performed with the following program package: TEXSAN, version 6.0; Molecular Structure Corp.: The Woodlands, TX, 1990.
16. Least-squares refinements were done with the following program package: SHELXTL-PLUS; Siemens Analytical X-ray Instruments Inc.: Madison, WI, 1990.
17. Ziebarth, R. P.; Corbett, J. D. J. Am. Chem. Sac. 1985, 107, 4571
18. Ziebarth, R. P. Ph.D. Dissertation, Iowa State University, 1987.
19. Sheldrick, G. M. SHELX-86. Universität Göttingen, Germany, 1986.
20. Corbett, J. D. J. Solid State Chem. 1981, 37, 335.
21. Ziebarth, R. P.; Corbett, J. D. J. Solid State Chem. 1989, 80, 56.
22. Hughbanks, T.; Rosenthal, G.; Corbett, J. D Inorg. Chem. 1988, 110, 1511.
23. Ziebarth, R. P.; Corbett, J. D. J. Am. Chem. Soc. 1989, 111, 3272.
24. A third longer intercluster I1⋯I2 contact about each atom type occurs in the same halogen layer and ranges between 4.066 and 3.995 Å over the series in Table 4. This lies about normal to the rhomboid connections seen in Figure 2 and involves 12 in a cluster in the third layer.
25. Dudis, D. S., Corbett, J. D.; Hwu, S -J. Inorg. Chem. 1986, 25, 3434.
26. Simon, A.; Mattausch, Hj.; Miller, G. J.; Bauhofer, W.; Kremer, R. K. In Handbook on the Physics and Chemistry of Rare Earths; Gschneider, K. A., Jr., Eyring, L , Eds.; North Holland: Amsterdam, 1991; Vol. 15, p 191.
27. Hughbanks, T.; Corbett, J. D. Inorg. Chem. 1988, 27, 2022.
28. Park, Y.; Corbett, J. D. Inorg. Chem. 1994, 33, 1705.
29. 13B lattice constants, since the greater disparity between a and b in the latter indicates a greater twisting of the chain linkages. Also, the substitution of I is presumably correlated on a short range, since neighboring I⋯I distances otherwise would be 3.75 Å intrachain and 3.72 Å interchain.