Oxidative-addition to a four-coordinate tin(II) complex supported by octamethyldibenzotetraaza[14]annulene dianion ligation, [η4-Me8taa]Sn: The syntheses and structures of [η4-Me8taa]sni2 and {[η4-Me8taa]SnI(THF)}{l3}

Polyhedron

Volumn 15, Issue 24, 1996, Pages 4599-4602

  Kuchta, Matthew C ^a   Parkin, Gerard ^a  

^a Columbia University ^*  (United States)

Author keywords

Iodine; Macrocycle; Oxidative addition; Tetraaza 14 annulene; Tin; X ray structure

Indexed keywords

EID: 0039015427     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/0277-5387(96)00204-5     Document Type: Article

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15. 2. See : M. C. Kuchta and G. Parkin, submitted.
16. 3, Z = 2. Atomic coordinates have been deposited with the Cambridge Crystallographic Data Centre.
17. 2 also exhibit a trans arrangement. See reference 13.
18. 1H NMR studies, but has not been confirmed by X-ray diffraction.
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29. 4 plane to a small degree.
30. 4 plane. See reference 13.
31. The range and mean values for Sn - I bond lengths listed in the Cambridge Structural Database (version 5.09) are 2.54-3.23 and 2.79 Å, respectively.
32. 3, Z = 4. Atomic coordinates have been deposited with the Cambridge Crystallographic Data Centre.
33. Cambridge Structural Database (Version 5.09).