Interconnective host-guest complexation of β-cyclodextrin- calix[4]arene couples

Journal of the American Chemical Society

Volumn 121, Issue 1, 1999, Pages 28-33

  Bügler, Jürgen ^a   Sommerdijk, Nico A J M ^b   Visser, Antonie J W G ^c   Van Hoek, Arie ^c   Nolte, Roeland J M ^b   Engbersen, Johan F J ^a   Reinhoudt, David N ^a  

^a UNIVERSITY OF TWENTE   (Netherlands)

^b RADBOUD UNIVERSITY NIJMEGEN   (Netherlands)

^c WAGENINGEN UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

BETA CYCLODEXTRIN DERIVATIVE; CALIXARENE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CYCLIZATION; FLUORESCENCE MICROSCOPY; HYDROGEN BOND; LIGHT SCATTERING; TRANSMISSION ELECTRON MICROSCOPY;

EID: 0038986910     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9828657     Document Type: Article

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21. i.
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25. For spherical rotation the volume of the rotating unit V is related via the Stokes-Einstein equation to the measured rotation correlation time φ where η is the viscosity of the solution, k is the Boltzmann constant, and T is the absolute temperature: φ = ηV/kT. In our case the viscosity of plain water was taken as an approximation for the viscosity of the very dilute solutions of 1 and 2.
26. 2 = 60 and 80 ns is not significant.
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