메뉴 건너뛰기




Volumn 105, Issue 6, 1996, Pages 2263-2279

Solvent-solute reaction path curvature effects on energy transfer corrections to the solute reaction rate

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0038965225     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.472095     Document Type: Article
Times cited : (10)

References (56)
  • 1
    • 85033857557 scopus 로고    scopus 로고
    • note
    • In our work, the time scale of the friction kernel remains constant as the static friction coefficient is increased [in contrast to the Straub, Borkovec, and Berne friction kernel (Ref. 9)]. As a result, the term weak (strong) damping, which refers to the magnitude of the static friction coefficient, is qualitatively synonymous with the term weak (strong) coupling, which refers more directly to the progression along the Kramer's turnover curve and is defined by the parameter ∈ [Eq. (18)].
  • 3
    • 0003428968 scopus 로고
    • edited by P. Hänggi and G. Fleming World Scientific, Singapore
    • E. Pollak, in Activated Barrier Crossing, edited by P. Hänggi and G. Fleming (World Scientific, Singapore, 1992).
    • (1992) Activated Barrier Crossing
    • Pollak, E.1
  • 7
    • 0000925532 scopus 로고
    • edited by M. Baer Chemical Rubber, Boca Raton, FL
    • J. T. Hynes, in Theory of Chemical Reaction Dynamics, edited by M. Baer (Chemical Rubber, Boca Raton, FL, 1985), p. 171.
    • (1985) Theory of Chemical Reaction Dynamics , pp. 171
    • Hynes, J.T.1
  • 10
    • 0000076281 scopus 로고
    • J. E. Straub, M. Borkovec, and B. J. Berne, J. Chem. Phys. 83, 3172 (1985); 84, 1788 (1986); 86, 1079E (1986).
    • (1986) J. Chem. Phys. , vol.84 , pp. 1788
  • 11
    • 0000712407 scopus 로고
    • J. E. Straub, M. Borkovec, and B. J. Berne, J. Chem. Phys. 83, 3172 (1985); 84, 1788 (1986); 86, 1079E (1986).
    • (1986) J. Chem. Phys. , vol.86
  • 22
  • 39
    • 85033865408 scopus 로고    scopus 로고
    • note
    • More precisely, γ(t) is associated with the effect of the pure solvent modes on the pure solute coordinate, see Ref. 25.
  • 43
    • 85033833976 scopus 로고    scopus 로고
    • note
    • 1 is neglected.
  • 47
    • 85033852044 scopus 로고    scopus 로고
    • personal communication
    • E. Pollak (personal communication).
    • Pollak, E.1
  • 50
    • 0003860192 scopus 로고
    • edited by J. U. Brackbill and B. I. Cohen Academic, New York
    • B. J. Berne, in Multiple Time Scales, edited by J. U. Brackbill and B. I. Cohen (Academic, New York, 1985).
    • (1985) Multiple Time Scales
    • Berne, B.J.1
  • 53
    • 85033842647 scopus 로고    scopus 로고
    • note
    • We give the form of X which is specific to the (p,σ) normal mode transformation here. See Ref. 28 for more details.
  • 55
    • 85033833906 scopus 로고    scopus 로고
    • note
    • We ignore the one discontinuity which occurs at the energy for which ∂g/∂σ(Ẽ) is double valued in E.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.