BABAR-PHOS-rhodium complexes: Reversible metal insertion into a three-membered ring and catalytic hydroborations

Angewandte Chemie - International Edition

Volumn 39, Issue 14, 2000, Pages 2478-2481

  Liedtke, Jürgen ^a   Rüegger, Heinz ^a   Loss, Sandra ^a   Grützmacher, Hansjörg ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

Homogeneous catalysis; Hydroborations; Phosphorus; Phosphorus heterocycles; Rhodium

Indexed keywords

METAL; PHOSPHINE DERIVATIVE; RHODIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; REACTION ANALYSIS;

EID: 0038957307     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20000717)39:14<2478::AID-ANIE2478>3.0.CO;2-G     Document Type: Article

References (20)

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19. 31P NMR signals appeared in the region of the intact BABAR-Phos ligand. However, we have been unable to isolate any pure product yet.
20. 2. However, one could circumvent catalyst destruction by separation before workup.