Stereochemical consequences of the bismuth atom electron lone pair, a comparison between MX6E and MX6 systems. Crystal and molecular structures of tris[N-(P,P-diphenylphosphinoyl)-P,P- diphenylphosphinimidato]bismuth(III),[Bi{(OPPh2)2N} 3], -indium(III),[In{(OPPh2)2N}3 ]·C6H6

Inorganic Chemistry

Volumn 35, Issue 13, 1996, Pages 3948-3953

  García Montalvo, Verónica ^a   Cea Olivares, Raymundo ^a   Williams, Daniel J ^b   Espinosa Pérez, Georgina ^a  

^a UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

^b KENNESAW STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0038841847     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9512082     Document Type: Article

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53. 2 ligands indicates that the small differences observed in the coordination geometry may be rationalized without invoking a stereoactive lone pair. For example, the distonions in the indium(III) complexes are caused by the small bite of such ligands: (a) Svensson, G., Albertsson, J. Acta Chem. Scand 1989, 43, 511. (b) Cogeon, P.; Lebeda, J. D.; McPhail, A. T.; Palmer, R A. J. Chem. Soc., Chem. Commun. 1970, 78. (c) Hauser, P. J.; Bordner, J.; Schreiner, A. F. Inorg. Chem. 1973, 12, 1347. (d) Bhattacharya, S.; Seth, N.; Gupta, V. D.; Nöth, H.; Thomann, M. Z. Naturforsch 1994, 49b, 193.
54. b set.
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