Electrochemical and XPS studies toward the role of monomeric and polymeric sulfonate counterions in the synthesis, composition, and properties of poly(3,4-ethylenedioxythiophene)

Macromolecules

Volumn 36, Issue 9, 2003, Pages 3337-3344

  Zotti, G ^a   Zecchin, S ^a   Schiavon, G ^a   Louwet, F ^b   Groenendaal, L ^b   Crispin, X ^c   Osikowicz, W ^c   Salaneck, W ^c   Fahlman, M ^c  

^a CNR   (Italy)

^b AGFA GEVAERT N V   (Belgium)

^c LINKÖPING UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDITY; ALKALINITY; COMPOSITION EFFECTS; CYCLIC VOLTAMMETRY; DOPING (ADDITIVES); ELECTROCHEMISTRY; IONS; MONOMERS; SYNTHESIS (CHEMICAL); ULTRAVIOLET SPECTROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

MONOMERIC SULFONATE COUNTERIONS; NANOMETER SCALE SEGREGATION; NUCLEOPHILIC CHARACTER; POLYETHYLENDIOXYTHIOPHENE; POLYMER SYNTHESIS; POLYMERIC SULFONATE COUNTERIONS;

POLYETHYLENES;

EID: 0038779603     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma021715k     Document Type: Article

References (24)

1. For a review on PEDT and derivatives, see: Groenendaal, L.; Jonas, F.; Freitag, D.; Pielartzik, H.; Reynolds, J. R. Adv. Mater. 2000, 12, 481.
2. Lefebvre, M.; Qi, Z.; Rana, D.; Pickup, P. G. Chem. Mater. 1999, 11, 262.
3. Li, G.; Pickup, P. G. Phys. Chem. Chem. Phys. 2000, 2, 1255.
4. Sotzing, G. A.; Reynolds, J. R.; Steel, P. J. Adv. Mater. 1997, 9, 795.
5. Zotti, G.; Zecchin, S.; Schiavon, G.; Groenendaal, L. Chem. Mater. 2000, 12, 2996.
6. Scienta ESCA200 User's Manual; Scientia: Uppsala, Sweden.
7. Sherwood, P. M. A. Auger and X-ray Photoelectron Spectroscopy; 2nd ed. Chichester, England, 1990; Vol. 1.
8. Beamson, G.; Briggs, D. High-Resolution XPS of Organic Polymers: The Scienta ESCA 300 database; Scientia: Uppsala, Sweden, 1992.
9. Wynne, K. J.; Street, G. B. Macromolecules 1985, 18, 2361.
10. Zotti, G.; Schiavon, G.; Zecchin, S.; Sannicolo', F.; Brenna, E. Chem. Mater. 1995, 7, 1464.
11. Bard, A. J.; Faulkner, L. R. in Electrochemical Methods; Bard, A. J., Ed.; Wiley: New York, 1980.
12. Furukawa, Y.; Akimoto, M.; Harada, I. Synth. Met. 1987, 18, 151.
13. Zotti, G.; Schiavon, G.; Berlin, A.; Pagani, G. Chem. Mater. 1993, 5, 620.
14. Xu, Z.; Fichou, D.; Horowitz, G.; Garnier, F. J. Electroanal. Chem. 1989, 267, 339.
15. Erlich, R. H.; Popov, A. I. J. Am. Chem. Soc. 1971, 93, 5620.
16. Bredas, J. L.; Silbey, R.; Boudreaux, D. S.; Chance, R. R. J. Am. Chem. Soc. 1983, 105, 6555.
17. Kim, J. Y.; Jung, J. H.; Lee, D. E.; Joo, J. Synth. Met. 2002, 126, 311.
18. McDiarmid, A. G.; Epstein, A. J. Synth. Met. 1994, 65, 103.
19. Xia, J. Y.; Wiesinger, J. M.; McDiarmid, A. G. Chem. Mater. 1995, 7, 443.
20. Greczynski, G.; Kugler, T.; Salaneck, W. R. Thin Solid Films 1999, 354, 129.
21. Greczynski, G.; Kugler, T.; Keil, M.; Osikowicz, W.; Fahlman, M.; Salaneck, W. R. J. Electron Spectrosc. Relat. Phenom. 2001, 121, 1.
22. Aasmundtveit, K. E.; Samuelsen, E. J.; Petersson, L. A. A.; Inganäs, O.; Johansson, T.; Feidenhans, R. Synth. Met. 1999, 101, 561.
23. Brédas, J. L.; Calbert, J. P.; Filho, D. A. d. S.; Cornil, J. PNAS 2002, 99, 5804.
24. Crispin, X.; Osikowicz, W.; Zotti, G.; Fahlman, M.; Salaneck, W. R. Manuscript in preparation.