Water-soluble polymer-bound biomimetic analogues of cytochrome c oxidase catalyze 4e- reduction of O2 to water

Inorganic Chemistry

Volumn 42, Issue 11, 2003, Pages 3384-3386

  Collman, James P ^a   Fudickar, Werner ^a   Shiryaeva, Irina ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; CYTOCHROME C OXIDASE; HEME; OXYGEN; POLYACRYLIC ACID; POLYMER; PORPHYRIN; POVIDONE;

AQUEOUS SOLUTION; ARTICLE; BIOMIMETICS; CATALYSIS; CHEMICAL STRUCTURE; CYCLIC POTENTIOMETRY; OXIDATION; PH; POLYMERIZATION; REACTION ANALYSIS; REDUCTION;

CATALYSIS; ELECTROCHEMISTRY; ELECTRON TRANSPORT COMPLEX IV; IRON; METALLOPORPHYRINS; MOLECULAR MIMICRY; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; OXYGEN; POLYMERS; WATER;

EID: 0038779382     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034140w     Document Type: Article

References (17)

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2. Collman, J. P.; Sunderland, C. J.; Boulatov, R. Inorg. Chem. 2002, 41, 2282.
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6. 2+ as the electron mediator: Anson, F. C.; Ni, C. L.; Saveant, J. M. J. Am. Chem. Soc. 1985. 107, 3442 and references therein.
7. 2+ as the electron mediator: Anson, F. C.; Ni, C. L.; Saveant, J. M. J. Am. Chem. Soc. 1985. 107, 3442 and references therein.
8. 2+ as the electron mediator: Anson, F. C.; Ni, C. L.; Saveant, J. M. J. Am. Chem. Soc. 1985. 107, 3442 and references therein.
9. 2+ as the electron mediator: Anson, F. C.; Ni, C. L.; Saveant, J. M. J. Am. Chem. Soc. 1985. 107, 3442 and references therein.
10. See Supporting Information for further details.
11. Collman, J. P.; Brauman, J. I.; Doxsee, K. M.; Halbert, T. R.; Bunnenberg, E.; Linder, R. E.; Lamar, G. N.; Delgaudio J.; Lang, G.; Spartalian, K. J. J. Am. Chem. Soc. 1980, 102, 4182.
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13. At pH 7 only Fe-1-PAA gave reproducible results; Fe-1-PVP and Fe-2-PVP could not be studied at higher pH.
14. 2.
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16. 2 with n > 2 at sufficiently reducing potentials; see for example: Shigehara, K.; Anson, F. C. J. Phys. Chem. 1982, 86, 2776 and ref 1 above.
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