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85031175448
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note
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Compound 1a was prepared by first dissolving LiTCNQ (2.570 mmol) in 20 mL of MeCN, followed by addition of a solution of N-octyl-4-methylpyridinium bromide (1.283 mmol) in 5 mL of MeCN. At reflux DBU (2.570 mmol) was added in increments of three drops every 15 min. After 14 h the reaction was stopped and the precipitate was filtered, washed with MeCN and dried under vacuum. The crude product was purified by washing with boiling methanol (70 mL) in a beaker, followed by filtering the undissolved portion. The process was repeated four times before the undissolved product was pure as analyzed by UV-vis.
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12
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85031175577
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note
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-1): 2132, 2175 (C*N).
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13
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85031169403
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note
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-1): 2129, 2176 (C*N).
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14
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17
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16944365315
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