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a) It is known that the carboxylic acid-N-base proton transfer equilibria are strongly favoured in chlorinated solvents such as dichloromethane or chloroform. See for example: Kraemer R and Zundel G. J. Chem. Soc. Faraday Trans. 1990; 86: 301-305, and references therein.
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ei are relative to the acid-base and the subsequent electrostatic interaction equilibria, respectively.
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For some excellent, recent overviews on the role of hydrogen bonding in supramolecular chemistry see: a) Prins LJ, Reinhoudt DN and Timmerman P. Angew. Chem., Int. Ed. 2001; 40: 2383-2426. b) Sherrington DC and Taskinen KA. Chem. Soc. Rev. 2001; 30: 83-93.
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The UV-vis spectral changes, upon addition of this ligand to 2Zn, are similar to that observed for 4,4′-bpy. This indicates the occurrence of an interaction via coordination of both of nitrogen sites and, concomitantly, a 1:1 complex formation.
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45
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a) Hunter CA and Sanders JKM. J. Am. Chem. Soc. 1990; 112: 5525-5534. For recent reports on the quantification of π-π stacking interactions in hydrogen bonding self assembled aromatic suprastructures see: b) Adams H, Hunter CA, Lawson KR, Perkins J, Spey SE, Urch CJ and Sanderson JM. Chem.Eur. J. 2001; 7: 4863-4877. c) Carver FJ, Hunter CA, Livingstone DJ, McCabe JF and Seward EM. Chem.Eur. J. 2002; 8: 2847-2859, and references therein.
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If a polymerisation was occurring in a linear fashion via a series of simple 1:1 binding events the apparent association constant would show only a moderate increase of K. For some recent examples related to porphyrin chemistry see: a) Twyman LJ and King ASH. Chem. Commun. (Cambridge, U. K.) 2002: 910-911. b) Drain CM, Shi XX, Milic T and Nifiatis F. Chem. Commun. (Cambridge, U. K.) 2001; 3: 287-288. c) For a quantitative approach to the problem see: Ercolani G. Chem. Commun. (Cambridge, U. K.) 2001: 1416-1417.
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If a polymerisation was occurring in a linear fashion via a series of simple 1:1 binding events the apparent association constant would show only a moderate increase of K. For some recent examples related to porphyrin chemistry see: a) Twyman LJ and King ASH. Chem. Commun. (Cambridge, U. K.) 2002: 910-911. b) Drain CM, Shi XX, Milic T and Nifiatis F. Chem. Commun. (Cambridge, U. K.) 2001; 3: 287-288. c) For a quantitative approach to the problem see: Ercolani G. Chem. Commun. (Cambridge, U. K.) 2001: 1416-1417.
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If a polymerisation was occurring in a linear fashion via a series of simple 1:1 binding events the apparent association constant would show only a moderate increase of K. For some recent examples related to porphyrin chemistry see: a) Twyman LJ and King ASH. Chem. Commun. (Cambridge, U. K.) 2002: 910-911. b) Drain CM, Shi XX, Milic T and Nifiatis F. Chem. Commun. (Cambridge, U. K.) 2001; 3: 287-288. c) For a quantitative approach to the problem see: Ercolani G. Chem. Commun. (Cambridge, U. K.) 2001: 1416-1417.
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