[RuCl(η5-C5H5)(PPh3) 2] as catalyst in the reaction of primary amines with diaryl diazoalkanes: Unexpected formation of Ar2C=NR compounds

Inorganica Chimica Acta

Volumn 349, Issue , 2003, Pages 249-252

  Del Zotto, Alessandro ^a   Baratta, Walter ^a   Miani, Francesca ^a   Verardo, Giancarlo ^a   Rigo, Pierluigi ^a  

^a UNIVERSITY OF UDINE   (Italy)

Author keywords

Amines; Carbene complexes; Diazoalkanes; Homogeneous catalysis; Imines; Ruthenium cyclopentadienyl complexes

Indexed keywords

CATALYSIS; CHLORINE COMPOUNDS; RUTHENIUM COMPOUNDS;

CARBENE COMPLEXES; CYCLOPENTADIENYL COMPLEXES; DIAZOALKANES; HOMOGENEOUS CATALYSIS; IMINES;

AMINES;

ALKANE DERIVATIVE; AMINE; ARGON; CARBENE; CHLOROFORM; RUTHENIUM COMPLEX;

ARTICLE; CATALYSIS; CATALYST; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; TEMPERATURE;

EID: 0038730408     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(03)00044-6     Document Type: Article

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11. 5).
12. 2 in almost all experiments have been detected by GC-MS
13. 2 and trace amounts of PhCH=NH, as inferred from GC-MS analyses. These results seem to suggest that both hydrazine and ammonia should be generated in the reaction mixtures.