Transition states of homologous SN′ reactions of all-(E)-polyenolate derivatives

Bulletin of the Korean Chemical Society

Volumn 24, Issue 3, 2003, Pages 265-266

  Park, Gyoosoon ^a  

^a Kookmin University   (South Korea)

Author keywords

Ab initio; Anti syn; SN Reactions; Stereochemistry

Indexed keywords

ALLYL COMPOUND; POLYENE; POLYENOLATE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CALCULATION; CHEMICAL REACTION; CORRELATION ANALYSIS; ELECTRICITY; MOLECULAR INTERACTION; PHASE TRANSITION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0038690476     PISSN: 02532964     EISSN: None     Source Type: Journal    
DOI: 10.5012/bkcs.2003.24.3.265     Document Type: Article

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12. ω carbon. It is a typical SN′ reaction for the number of vinyl chain ('n') is one.
13. It has been predicted that Nu's are to be attached in an alternation manner: syn-mode for C3 and anti-mode for C5 in C5=C4 C3=C2-C1-X system. See ref. 3a.
14. Frisch, M. J. et al. Gaussian 98, Revision A.7; Gaussian, Inc.: Pittsburgh, PA, 1998.