Acid-catalyzed rearrangement of epoxy alcohol derivatives having the electron-withdrawing protective groups (acyl or sulfonyl): Asymmetric synthesis of chiral quaternary carbon and spiro centers and its application to natural products synthesis

Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry

Volumn 61, Issue 2, 2003, Pages 133-143

  Fujioka, H ^b   Yoshida, Yutaka ^b   Kita, Yasuyuki ^a  

^a OSAKA UNIVERSITY   (Japan)

^b NONE

Author keywords

(+) (S) sporochnol A; ( ) aphanorphine; ( ) herbertenol; Asymmetric synthesis; Chiral quaternary carbon; Chiral spiro center; Epoxy acylate; Epoxy sulfonate; Fredericamycin A; Rearrangement

Indexed keywords

ACIDS; CARBON; DERIVATIVES; SYNTHESIS (CHEMICAL);

ACID-CATALYZED REARRANGEMENT; APHANORPHINE; CHIRAL QUATERNARY CARBON; CHIRAL SPIRO CENTER; ELECTRON-WITHDRAWING PROTECTIVE GROUPS; EPOXY ALCOHOL DERIVATIVES; FREDERICAMYCIN A; HERBERTENOL; SPOROCHNOL A;

ALCOHOLS;

EID: 0038682018     PISSN: 00379980     EISSN: None     Source Type: Journal    
DOI: 10.5059/yukigoseikyokaishi.61.133     Document Type: Article

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