Predicting heats of combustion of polymers using an empirical approach

Fire and Materials

Volumn 27, Issue 1, 2003, Pages 9-17

  Hshieh, Fu Yu ^a   Hirsch, David B ^a,b   Beeson, Harold D ^b  

^a Honeywell Technology Solutions Inc   (United States)

^b NASA JOHNSON SPACE CENTER   (United States)

Author keywords

Empirical approach; Heats of combustion; Organic polymers; Silicone polymers

Indexed keywords

MOLECULAR WEIGHT; MONOMERS; ORGANIC POLYMERS; REGRESSION ANALYSIS; SILICON COMPOUNDS; SILICONES;

ATOMIC CONTRIBUTION; HEATS OF COMBUSTION; MULTIPLE LINEAR REGRESSION METHOD; ORGANOSILICON COMPOUNDS;

COMBUSTION;

EID: 0038636538     PISSN: 03080501     EISSN: None     Source Type: Journal    
DOI: 10.1002/fam.815     Document Type: Article

References (11)

1. Benson SW, Cruickshank FR, Golden DM, O'Neal HE, et al., Chemical Reviews 1969; 69:279.
2. Benson SW, Methods for the estimation of thermochemical data and rate parameters. Thermochemical Kinetics, 2nd edn. John Wiley: New York, 1976.
3. Walters RN, Mackett SM, Lyon RE, Heats of combustion of high temperature polymers. Fire and Materials 2000; 24:245-252.
4. Huggett C. Estimation of rate of heat release by means of oxygen consumption measurements. Fire and Materials 1980: 4:61-65.
5. Babrauskas V. Related quantities (a) heat of combustion and potential heat. In Heat Release in Fires, Babrauskas V, Grayson SJ, (eds.). Elsevier Applied Science: London, 1992; 207-223.
6. Hshieh FY, Predicting heats of combustion and lower flammability limits of organosilicon compounds. Fire and Materials 1999; 23:79-89.
7. Hajiev SN, Kerimov KK, Hajieva FS, Ignatyev VL, Journal of Chemical Thermodynamics 1980; 12:509-519.
8. Leonidov VY, Timofeev EV, Kiselev UM, Paper N 10. Conference on Calorimetry and Chemical Thermodynamics, Ivanovo, 1979.
9. Voronkov MG, Baryshok VP, Klyuchnikov VA, Danilova TF, Pepekin VI, Korchagina AN, Thermochemistry of organosilicon compounds I. Triorganyl-, tetraorganyl-, organylorganoxy- and tetraorganoxy-silanes. Journal of Organometallic Chemistry 1988; 345:27-38.
10. Daubert TE, Danner RP, Physical and Thermodynamic Properties of Pure Chemicals. Design Institut for Physical Property Research, DIPPER Data Compilation. Taylor & Francis: Bristol, PA. 1995.
11. Hshieh FY, Beeson HD, Note: Measuring the effective heats of combustion of transformer-insulating fluids using a controlled-atmosphere cone calorimeter. Fire and Materials 2002; 26:47-49.