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It has to be noted that the interfacial tensions of a liquid/air interface or liquid/solid interface can be significantly influenced by the presence of a second liquid, e.g. if the second liquid is forming a monomolecular layer on the interface formed by the other two phases. Throughout the text we assume that all interfacial tensions are acquired in equilibrium with both liquids being present.
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These lateral forces originate from the curved interfaces occurring if the volume of the liquid is less than the volume of the particles. They are absent in the case of the planar fluid/fluid interfaces considered here.
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If a mixture of oil and particles is spread with the aid of a wetting volatile solvent, one might prepare a metastable layer that does not dewet from the water surface due to the contact angle hysteresis; on the other hand if the non-wetting oil and the particles are applied as pure substances to a water surface, the hysteresis might reduce the wetting tendency of the mixture.
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