Efficient palladium-catalyzed synthesis of the styrene intermediate of a novel herbicide, indanofan

Synthesis

Volumn , Issue 9, 2003, Pages 1321-1323

  Hosokawa, Akemi ^a   Yoshida, Kenji ^a  

^a MITSUBISHI CHEMICAL CORPORATION   (Japan)

Author keywords

Allenes; Condensation; Coupling; Heck reaction; Palladium

Indexed keywords

CATALYSIS; HERBICIDES; PALLADIUM; REACTION KINETICS; SYNTHESIS (CHEMICAL);

REACTION INTERMEDIATES;

STYRENE;

1,3 INDANDIONE DERIVATIVE; 2 (3 CHLOROPHENYL)PROP 2 EN 1 OL; 2 ETHYLINDAN 1,3 DIONE; 2 [2 (3 CHLOROPHENYL)ALLYL] 2 ETHYLINDAN 1,3 DIONE; 3 BROMOCHLOROBENZENE; ALCOHOL DERIVATIVE; ALLENE DERIVATIVE; HERBICIDE; INDANOFAN; PALLADIUM; STYRENE DERIVATIVE; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CATALYSIS; CATALYST; GAS CHROMATOGRAPHY; HECK REACTION; INFRARED RADIATION; MOLECULAR INTERACTION; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SEPARATION TECHNIQUE; SYNTHESIS;

EID: 0038575282     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-40200     Document Type: Article

References (9)

1. Hosokawa, A.; Shike, T.; Ikeda, O.; Katsurada, M.; Minami, N.; Jikihara, T. J. Pesticide Sci. 2001, 26, 41.
2. Tanaka, K.; Hosokawa, A.; Yoshida, K. Synthesis 1999, 249.
3. (a) Atkins, K. E.; Walker, W. E.; Manyik, R. M. Tetrahedron Lett. 1970, 43, 3821.
4. (b) For review, see: Tsuji, J. Tetrahedron 1986, 42, 4361.
5. (c) Trost, B. M. Tetrahedron 1977, 33, 2615.
6. 2O (1 L). The precipitate was filtered off, and recrystallized from EtOH to give sulfonated phosphine (8 g).
7. Ahmar, M.; Cazes, B.; Gore, J. Tetrahedron Lett. 1984, 25, 4505.
8. Chem. Abstr. 1995, 123, 339398.
9. Cripps, H. N.; Kiefer, E. F. Org. Synth., Coll. Vol. 5; Wiley: New York, 1973, 22.