An investigation into the relative influence of alkoxide and thiolate ligands on the metal-carbon triple bond in X3M≡CH compounds, where M = CR, MO and W and X = OH, SH, OCH3, SCH3, OCF3 and SCF3 from electronic structure calculations

Polyhedron

Volumn 22, Issue 1, 2003, Pages 145-152

  Chisholm, Malcolm H ^a   Davidson, Ernest R ^b   Quinlan, Kristine B ^b  

^a OHIO STATE UNIVERSITY   (United States)

^b INDIANA UNIVERSITY   (United States)

Author keywords

Alkoxide; Electronic structure; Frontier molecular orbitals; Molybdenum alkylidyne; Thiolate; Tungsten alkylidyne

Indexed keywords

CARBON; LIGAND; METAL;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; DECOMPOSITION; DISSOCIATION CONSTANT; ELECTRIC CONDUCTIVITY; LIGAND BINDING; MOLECULAR INTERACTION; STRUCTURE ANALYSIS;

EID: 0038573743     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(02)01260-3     Document Type: Article

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