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Volumn 44, Issue 29, 2003, Pages 5553-5556

Arabidopsides A and B, two new oxylipins from Arabidopsis thaliana

Author keywords

12 oxophytodienoic acid; Arabidopsis thaliana; Natural products; Oxylipins; Plants

Indexed keywords

12 OXOPHYTODIENOIC ACID; ARABIDOPSIDES A; ARABIDOPSIDES B; CHEMICAL COMPOUND; DIACYLGLYCEROL DERIVATIVE; DINOROXOPHYTODIENOIC ACID; PLANT EXTRACT; UNCLASSIFIED DRUG;

EID: 0038539416     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(03)01148-1     Document Type: Article
Times cited : (73)

References (12)
  • 2
    • 85031155747 scopus 로고    scopus 로고
    • note
    • max 222 (ε 11000) nm.
  • 3
    • 0017420652 scopus 로고
    • The allylic carbons of cis- and trans-double bonds in the aliphatic chains are reported to resonate approximately at 27 and 32 ppm, respectively:
    • The allylic carbons of cis- and trans-double bonds in the aliphatic chains are reported to resonate approximately at 27 and 32 ppm, respectively: Gunstone F.D., Pollard M.R., Scrimgeour C.M., Vedanayagam H.S. Chem. Phys. Lipids. 18:1977;115-129.
    • (1977) Chem. Phys. Lipids , vol.18 , pp. 115-129
    • Gunstone, F.D.1    Pollard, M.R.2    Scrimgeour, C.M.3    Vedanayagam, H.S.4
  • 7
    • 0031569411 scopus 로고    scopus 로고
    • Methanolysis of 1 and the chiral GC analyses of the methanolysates. After a solution of 1 (0.2 mg) in 0.6 mol/L HCl/MeOH (0.1 mL) was stirred at 60°C for 45 min, the solvent was removed under reduced pressure. The residue was partitioned with hexane and 90% MeOH and the hexane-soluble materials were used for chiral GC analyses. Chiral GC conditions, column: γ-DEX™ 120 Capillary Column, SUPELCO; program rate: 40→160°C (at 10°C/min), 160°C (360 min), 160→200°C (at 10°C/min), and 200°C (60 min). The absolute configurations of the OPDA and dinor-OPDA were determined by the retention time (min). The cis enantiomers, (7′′S,11′′S)-4 (238 min) and (7′′R,11′′R)-4 (238 min) and (9′′′S,13′′′S)-5 (397 min) and (9′′′R,13′′′R)-5 (397 min) were inseparable, respectively, while the trans enantiomers, (7′′S,11′′R)-4 (157 min) and (7′′R,11′′S)-4 (158 min) (10:3) and (9′′′S,13′′′R)-5 (359 min) and (9′′′R,13′′′S)-5 (363 min) (10:3), which were produced from cis forms by enolization. Laudert, D.; Hennig, P.; Stelmach, B. A.; Müller, A.; Andert, L.; Weiler, E. W. Anal. Biochem. 1997, 246, 211-217.
    • (1997) Anal. Biochem. , vol.246 , pp. 211-217
    • Laudert, D.1    Hennig, P.2    Stelmach, B.A.3    Müller, A.4    Andert, L.5    Weiler, E.W.6
  • 8
    • 85031151708 scopus 로고    scopus 로고
    • note
    • 2O, 1:1) to give the β-galactosylglycerol (6, 0.27 mg, 92%).
  • 10
    • 85031157368 scopus 로고    scopus 로고
    • note
    • max 225 (ε 13200) nm.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.