Synthesis of [RuX(CO){η2-C,N-C6H4C(H)= NC6H4-4-NO2}(PPh3)2] (X = F, Cl, Br, I): Evidence of non-conventional Ru-X hydrogen bonds leading to octahedral coordination at the halide atom

European Journal of Inorganic Chemistry

Volumn , Issue 10, 2003, Pages 1929-1938

  Flower, Kevin R ^a   Pritchard, Robin G ^a   Warren, John E ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Charge transfer; Cyclometallated ligands; Hydrogen bonds; Pi interactions; Ruthenium

Indexed keywords

ACETONE; BROMINE COMPOUNDS; CHARGE TRANSFER; CHELATION; CHLORINE COMPOUNDS; COMPLEXATION; FLUORINE COMPOUNDS; HYDROGEN BONDS; INDIUM COMPOUNDS; NITROGEN OXIDES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM; RUTHENIUM COMPOUNDS; SINGLE CRYSTALS; X RAY DIFFRACTION;

CATIONIC COMPLEXES; CYCLOMETALLATED LIGAND; DATA SUPPORT; H NMR SPECTROSCOPY; HALIDE ATOMS; IR DATA; IR-SPECTROSCOPY; OCTAHEDRAL COORDINATION; PI INTERACTIONS; SPECTROSCOPY:SPECTROSCOPY;

LIGANDS;

COORDINATION COMPOUND; RUTHENIUM COMPLEX;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL INTERACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; HYDROGEN BOND; INFRARED SPECTROSCOPY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0038509931     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200200527     Document Type: Article

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