Iminophosphorane mediated imine metathesis

Inorganic Chemistry

Volumn 42, Issue 11, 2003, Pages 3438-3444

  Burland, Matthew C ^a   Meyer, Tara Y ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYANAMIDE; HYDROCHLORIC ACID; IMINE; IMINOPHOSPHORANE; LEWIS ACID; PHOSPHORANE DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL BOND; DECOMPOSITION; ELIMINATION REACTION; STOICHIOMETRY; TEMPERATURE;

EID: 0038441464     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0263138     Document Type: Article

References (33)

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26. For a detailed discussion of iminophosphorane bonding and its relevance to the formally forbidden [2 + 2] reactions, see our previous work on iminophosphorane catalyzed carbodiimide metathesis, ref 7.
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28. Becke-Goehring, M.; Leichner, L.; Scharf, B. Z. Anorg. Allg. Chem. 1966, 343, 154-164. Fluck, E.; Wachtler, D. Liebigs. Ann. Chem. 1980, 1651-1658. Zhmurova, I. N.; Drach, B. S. Zh. Obsch. Khim. 1964, 34, 1441-1446. Zhmurova, I. N.; Kisilenko, A. A.; Kirsanov, A. V. Zh. Obsch. Khim. 1962, 32, 2580-2586.
29. Becke-Goehring, M.; Leichner, L.; Scharf, B. Z. Anorg. Allg. Chem. 1966, 343, 154-164. Fluck, E.; Wachtler, D. Liebigs. Ann. Chem. 1980, 1651-1658. Zhmurova, I. N.; Drach, B. S. Zh. Obsch. Khim. 1964, 34, 1441-1446. Zhmurova, I. N.; Kisilenko, A. A.; Kirsanov, A. V. Zh. Obsch. Khim. 1962, 32, 2580-2586.
30. Becke-Goehring, M.; Leichner, L.; Scharf, B. Z. Anorg. Allg. Chem. 1966, 343, 154-164. Fluck, E.; Wachtler, D. Liebigs. Ann. Chem. 1980, 1651-1658. Zhmurova, I. N.; Drach, B. S. Zh. Obsch. Khim. 1964, 34, 1441-1446. Zhmurova, I. N.; Kisilenko, A. A.; Kirsanov, A. V. Zh. Obsch. Khim. 1962, 32, 2580-2586.
31. Imines were prepared by stirring a benzene solution of the corresponding amine and aldehyde over molecular sieves, followed by filtration, removal of solvent in vacuo, and vacuum distillation, in the case of liquid imines, or recrystallization from hexane in the case of solid imines.
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