Photosensitization efficiencies of metallophthalocyanines for the formation of singlet oxygen

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 33, Issue 3, 2003, Pages 403-409

  Kasuga, Kuninobu ^a   Miyazako, Takahiro ^a   Sugimori, Tamotsu ^a   Handa, Makoto ^a  

^a SHIMANE UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1,3 DIPHENYLISOBENZOFURAN; BENZOFURAN DERIVATIVE; DIMETHYL SULFOXIDE; PHOTOSENSITIZING AGENT; PHTHALOCYANINE DERIVATIVE; SINGLET OXYGEN; UNCLASSIFIED DRUG;

AERATION; ARTICLE; CATALYSIS; DRUG ACTIVITY; IRRADIATION; KINETICS; PHOTOACTIVATION; PHOTODEGRADATION; PHOTOOXIDATION; PHOTOSENSITIZATION; POLARIZATION;

EID: 0038414611     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120019994     Document Type: Article

References (17)

1. Ferraudi, G. Phtalocyanines-Properties and Applications; Leznoff, C.C., Lever, A.B.P., Eds.; VCH: New York, 1989; 291-340.
2. Decreau, R.; Viola, A.; Richard, J.A.; Julliard, M. Photodynamic therapy: photosensitizing efficacy of bis(tri-n-hexylsiloxy)siliconphthalocyanine against achromic M6 melanocytes. J. Porphyrins Phthalocyanines 1998, 2, 405-414.
3. Kasuga, K.; Takahashi, S.; Tsukahara, K.; Ohno, T. Photoreduction of methylviologen catalyzed by phthalocyanine complexes of yttrium(III) and lanthanoid(III) metals. Inorg. Chem. 1990, 29, 354-356.
4. Kasuga, K.; Hayashi, H.; Handa, M. Photoreduction of methylviologen with a water-soluble phthalocyaninatozinc(II) complex in an aqueous solution. Chem. Lett. 1991, 1877-1880.
5. Kasuga, K.; Hayashi, H.; Miyasaka, H.; Handa, M.; Dairaku, M. Preparation and photocatalytic properties of an amphiphilic phtalocyaninatosilicon(IV) complex having methoxo ligands at its axial positions. Polyhedron 1995, 14, 1393-1395.
6. Kasuga, K.; Miyasaka, H.; Handa, M.; Dairaku, M. Photoreduction of methylviologen catalysed by tri- or tetra-sulphophtalocyaninatozinc(II) in aqueous solutions. Polyhedron 1995, 14, 1675-1679.
7. Kasuga, K.; Terauchi, M.; Hara, M.; Nishie, K.; Sugimori, T.; Handa, M. Photoreduction of hydrogencarbonate or ethylene catalyzed by trisodium trisulfonatophthalocyaninatozincate(II). Bull. Chem. Soc. Jpn. 1997, 70, 2107-2110.
8. Kasuga, K.; Fujita, A.; Miyazako, T.; Handa, M.; Sugimori, T. Photocatalytic decomposition of trichlorophenol by zinc(II) phthalocyanine derivatives in aerated organic solvents. Inorg. Chem. Commun. 2000, 3, 634-636.
9. Spiller, W.; Kliesch, H.; Wohre, D.; Hackbarth, S.; Roder, B.; Schnurpfeil, G. Singlet oxygen quantum yields of different photosensitizers in polar solvents and micellar solutions. J. Porphyrins Phthalocyanines 1998, 2, 145-158.
10. Ogilby, P.R.; Foote, C.S. Chemistry of singlet oxygen. 34. Unexpected solvent deuterium isotope effects on the lifetime of singlet molecular oxygen. J. Am. Chem. Soc. 1981, 103, 1219-1221.
11. Harriman, A.; Porter, G.; Richoux, M.-C. Photoreduction of methylviologen sensitized by the excited singlet state of a magnesium phthalocyanine. J. Chem. Soc., Faraday Trans. 2 1981, 77, 1175-1187.
12. In a visible spectrum, complex (5) showed the Q band for the monomer species at 675 nm with the band typical for the dimer one at 634 nm in DMSO.
13. Merkel, P.B.; Kearns, D.R. Remarkable solvent effects on the lifetime of singlet oxygen. J. Am. Chem. Soc. 1972, 94, 1029, 1030.
14. Gutmann, V.; Wychera, E. Coordination reactions in non aqueous solutions-the role of the donor strength. Inorg. Nucl. Chem. Lett. 1966, 2, 257-260.
15. The complexes of (2)-(4) were prepared according to the methods previously reported. For (2) and (4); Kasuga, K.; Hayashi, H.; Handa, M. Photoreduction of methylviologen with a water-souble phthalocyaninatozinc(II) complex in an aqueous solution. Chem. Lett. 1991, 1877-1880. For (3); Kasuga, K.; Asano, K.; Lin, L.; Sugimori, T.; Handa, M.; Abe, K.; Kikkawa, T.; Fujiwara, T. Preparation and some properties of one structural isomer of tetra-substituted phthalocyanine. Bull. Chem. Soc. Jpn., 1997, 70, 1859-1865. The preparation of the other complexes are described in the book: Leznoff, C.C. Phthalocyaninesins-Properties and Applications; Leznoff, C.C.; Lever, A.B.P., Eds.; VCH: New York, 1989; 1-54.
16. The complexes of (2)-(4) were prepared according to the methods previously reported. For (2) and (4); Kasuga, K.; Hayashi, H.; Handa, M. Photoreduction of methylviologen with a water-souble phthalocyaninatozinc(II) complex in an aqueous solution. Chem. Lett. 1991, 1877-1880. For (3); Kasuga, K.; Asano, K.; Lin, L.; Sugimori, T.; Handa, M.; Abe, K.; Kikkawa, T.; Fujiwara, T. Preparation and some properties of one structural isomer of tetra-substituted phthalocyanine. Bull. Chem. Soc. Jpn., 1997, 70, 1859-1865. The preparation of the other complexes are described in the book: Leznoff, C.C. Phthalocyaninesins-Properties and Applications; Leznoff, C.C.; Lever, A.B.P., Eds.; VCH: New York, 1989; 1-54.
17. The complexes of (2)-(4) were prepared according to the methods previously reported. For (2) and (4); Kasuga, K.; Hayashi, H.; Handa, M. Photoreduction of methylviologen with a water-souble phthalocyaninatozinc(II) complex in an aqueous solution. Chem. Lett. 1991, 1877-1880. For (3); Kasuga, K.; Asano, K.; Lin, L.; Sugimori, T.; Handa, M.; Abe, K.; Kikkawa, T.; Fujiwara, T. Preparation and some properties of one structural isomer of tetra-substituted phthalocyanine. Bull. Chem. Soc. Jpn., 1997, 70, 1859-1865. The preparation of the other complexes are described in the book: Leznoff, C.C. Phthalocyaninesins-Properties and Applications; Leznoff, C.C.; Lever, A.B.P., Eds.; VCH: New York, 1989; 1-54.