Anion partitioning in and diffusion through a Nafion membrane

Industrial and Engineering Chemistry Research

Volumn 42, Issue 15, 2003, Pages 3620-3625

  Huang, Kuo Lin ^a,c   Holsen, Thomas M ^a   Selman, J Robert ^b  

^a Clarkson University   (United States)

^b Illinois Institute of Technology   (United States)

^c CHANG JUNG CHRISTIAN UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINA; CERAMIC MATERIALS; DIFFUSION; NEGATIVE IONS;

NAFION MEMBRANES;

ION EXCHANGE MEMBRANES;

ALUMINUM OXIDE; ANION; CHROMIUM DERIVATIVE; COPPER SULFATE; FERRIC SULFATE; METAL OXIDE; NICKEL SULFATE;

ADSORPTION; CERAMICS; DIFFUSION; MEASUREMENT METHOD; MEMBRANE;

ADSORPTION; ARTICLE; CATION EXCHANGE; CERAMICS; DIFFUSION COEFFICIENT; ION EXCHANGE; IONIC STRENGTH; MEMBRANE; PARTITION COEFFICIENT; PH; TEMPERATURE SENSITIVITY;

EID: 0038383279     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030109q     Document Type: Article

References (33)

1. Lehmani, A.; Turq, P.; Perie, M.; Perie, J.; Simonin, J.-P. Ion transport in Nafion 117 membrane. J. Electroanal. Chem. 1997, 428, 81-89.
2. Samec, Z.; Trojanek, A.; Langmaier, J.; Samcova, E. Diffusion coefficients of alkali metal cations in Nafion from ion-exchange measurements: an advanced kinetic model. J. Electrochem. Soc. 1997, 144, 4236-4242.
3. Okada, T.; Xie, G.; Gorseth, O.; Kjelstrup, S.; Nakamura, N. Arimura, T. Ion and water transport characteristics of Nafion membranes as electrolytes. Electrochim. Acta 1998, 43, 3741-3747.
4. Grot, W. G. F. Nafion as a separator in electrolytic cells. Proc. Electrochem. Soc. 1986, 83, 1-12.
5. Verbrugge, M. W.; Hill, R. F. Ion and solvent transport in ion-exchange membranes: I. a macrohomogeneous mathematical model. J. Electrochem. Soc. 1990, 137, 886-893.
6. Verbrugge, M. W.; Hill, R. F. Ion and solvent transport in ion-exchange membranes: II. a radiotracer study of the sulfuric-acid, Nafion-117 system. J. Electrochem. Soc. 1990, 137, 893-899.
7. Capeci, S. W.; Pintauro, P. N.; Bennion, D. N. The molecular-level interpretation of salt uptake and anion transport in Nafion membranes. J. Electrochem. Soc. 1989, 136, 2876-2882.
8. Pourcelly, G.; Lindheimer, A. Gavach, C. Electrical transport of sulfuric acid in Nafion perfluorosulfonic membrane. J. Electroanal. Chem. 1991, 305, 97-113.
9. + through Nafion-117 ion exchange membrane. J. Radioanal. Nucl. Chem. 1996, 214, 399-409.
10. Huang, K. L.; Holsen, T. M.; Selman, J. R. Impurity diffusion through Nafion and ceramic separators used for electrolytic purification of spent chromium plating solutions. Accepted by J. Membr. Sci. May 2003.
11. Logette, S.; Eysseric, C.; Huguet, P.; Gavach, C. Pourcelly, G. Oxidation by electrogenerated mediator: Influence of perfluorosulfonic separator on process performance. J. Appl. Electrochem. 1999, 29, 371-381.
12. Mandich, N. V. Chemistry & theory of chromium deposition: part I - chemistry. Plat. Surf. Finish. 1997, 84 (May), 108-115.
13. Koryta, J.; Dvorak, J.; Kavan, L. Principles of Electrochemistry; John Wiley and Sons: New York, 1993; pp 105-134.
14. Hamann, C. H.; Hamnett, A.; Vielstich, W. Electrochemistry; Wiley-VCH: New York, 1998; pp 295-297.
15. Xue, T.; Longwell, R. B.; Osseo-Asare, K. Mass transfer in Nafion membrane systems: effects of ionic size and charge on selectivity. J. Membr. Sci. 1991, 58, 175-189.
16. Bontha, J. R.; Pintauro, P. N. Water orientation and ion solvation effects during multicomponent salt partitioning in a Nafion cation exchange membrane. Chem. Eng. Sci. 1994, 49, 3835-3851.
17. Huang, K. L.; Holsen, T. M.; Selman, J. R. Impurity partitioning in Nafion and ceramic separators used for electrolytic purification of spent chromium plating solutions. J. Membr. Sci. 2002, 210, 137-145.
18. Pintauro, P. N.; Tandon, R.; Chao, L.; Xu, W.; Evilia, R. Equilibrium partition of monovalent/divalent cation-salt mixtures in Nafion cation-exchange membranes. J. Phys. Chem. 1995, 99, 12915-12924.
19. Helfferich, F. Ion Exchange, 2nd ed.; Dover Publications: New York, 1995; pp 125-127.
20. Rollet, A.-L.; Simonin, J.-P.; Turq, P. Study of self-diffusion of alkali metal cations inside a Nafion membrane. Phys. Chem. Chem. Phys. 2000, 2, 1029-1034.
21. Juang, R.-S.; Yan, G.-S. Enhanced flux and selectivity of metals through a dialysis membrane by addition of complexing agents to receiving phase. J. Membr. Sci. 2001, 186, 53-61.
22. Newman, J. S. Electrochemical Systems; Prentice-Hall: Englewood Cliffs, NJ, 1991; pp 241-242.
23. Prentice, G. Electrochemical Engineering Principles; Prentice-Hall: Englewood Cliffs, NJ, 1991; pp 152-156.
24. Snoeyink V. L.; Jenkins D. Water Chemistry; John Wiley & Sons: New York, 1980; p 446.
25. Verbrugge, M. W.; Hill, R. F. Experimental and theoretical investigation of perfluorosulfonic acid membranes equilibrated with aqueous sulfuric acid solution. J. Phys. Chem. 1988, 92, 6778-6783.
26. Verbrugge, M. W.; Hill, R. F. Analysis of promising perfluorosulfonic acid membranes for fuel-cell electrolytes. J. Electrochem. Soc. 1990, 137, 3770-3777.
27. Guzman-Garcia, A. G.; Pintauro, P. N.; Verbrugge, M. W.; Hill, R. F. Development of a space-charge transport model for ion-exchange membranes. AIChE 1990, 36, 1061-1074.
28. Hoare, J. P. An electrochemical mystery story: a scientific approach to chromium plating. Plat. Surf. Finish. 1989, Sep, 46-52.
29. Yeo, S. C.; Eisenberg, A. Physical properties and supermolecular structure of perfluorinated ion-containing (Nafion) polymers. J. Appl. Polym. Sci. 1977, 21, 875-898.
30. Huang, R. Y. M.; Shao, P.; Nawawi, G.; Feng, X.; Burns, C. M. Measurements of partition, diffusion coefficients of solvents in polymer membranes using rectangular thin-channel column inverse gas chromatography (RTCCIGC). J. Membr. Sci. 2001, 188, 205-218.
31. Chang, H. T.; Ahmed, M. I. Personal communication, 1999.
32. Ramirez, W. F. Computational Methods for Process Simulation; Butterworth: Boston, 1989; pp 395-405.
33. Ahmed, M. I.; Chang, H. T.; Selman, J. R.; Holsen, T. M. Electrochemical chromic acid regeneration process: fitting of membrane transport properties. J. Membr. Sci. 2002, 197, 6374.