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Volumn 21, Issue 25, 2002, Pages 5622-5627

Synthesis, structures, and spectroscopy of the metallostannylenes (η5-C5H5)(CO)3M-S̈n-C6 H3-2,6-Ar2 (M = Cr, Mo, W.; Ar = C6H2-2,4,6-Me3, C6H2-2,4,6-Pr3i)

Author keywords

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Indexed keywords

CHEMICAL SHIFTS;

EID: 0038339034     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020583g     Document Type: Article
Times cited : (69)

References (45)
  • 7
    • 0012415911 scopus 로고    scopus 로고
    • April
    • Cambridge Crystallographic Data Centre: CSD version 5.23 (April 2002).
    • (2002) CSD Version 5.23
  • 10
    • 0034722220 scopus 로고    scopus 로고
    • Eichler, B. E.; Power, P. P. Inorg. Chem. 2000, 39, 5444. However, metallostannylenes with chelating ligands are known: Benet, S.; Cardin, C. J.; Cardin, D. J.; Constantine, S. P.; Heath, P.; Rashid, H.; Teixeira, S.; Thorpe, J. H.; Todd, A. K. Organometallics 1999, 18, 389.
    • (2000) Inorg. Chem. , vol.39 , pp. 5444
    • Eichler, B.E.1    Power, P.P.2
  • 20
    • 0001805131 scopus 로고
    • XABS2: An empirical absorption correction program
    • Parkin, S.; Moezzi, B.; Hope, H. XABS2: An Empirical Absorption Correction Program. J, Appl. Crystallogr. 1995, 28, 53.
    • (1995) J. Appl. Crystallogr. , vol.28 , pp. 53
    • Parkin, S.1    Moezzi, B.2    Hope, H.3
  • 21
    • 84977289324 scopus 로고
    • SADABS is an empirical absorption correction program using the method described by: Blessing, R. H. Acta Crystallogr. 1995, A51, 33. Sheldrick, G. M. SADABS; University of Göttingen, Göttingen, Germany, 1989.
    • (1995) Acta Crystallogr. , vol.A51 , pp. 33
    • Blessing, R.H.1
  • 22
    • 0004283942 scopus 로고
    • University of Göttingen, Göttingen, Germany
    • SADABS is an empirical absorption correction program using the method described by: Blessing, R. H. Acta Crystallogr. 1995, A51, 33. Sheldrick, G. M. SADABS; University of Göttingen, Göttingen, Germany, 1989.
    • (1989) SADABS
    • Sheldrick, G.M.1
  • 37
    • 0010297223 scopus 로고
    • 119 NMR: δ 277). No UV-vis data are currently available for these, but it can be reasonably expected that the n-p absorptions occur below 400 nm. (a) Barnhart, D. M.; Clark, D. L.; Watkin, J. G. Acta Crystallogr., Sect. C1994, 50, 702.
    • (1994) Acta Crystallogr., Sect. C , vol.50 , pp. 702
    • Barnhart, D.M.1    Clark, D.L.2    Watkin, J.G.3
  • 39
    • 0038212759 scopus 로고    scopus 로고
    • note
    • The reader will be aware that the n-p orbital energy separation is not the same as that of the singlet and triplet states, owing mainly to differing interelectronic repulsion in the ground and excited states.


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