Uncatalyzed Meerwein-Ponndorf-Verley reduction of trifluoromethyl carbonyl compounds by high-temperature secondary alcohols

Journal of Fluorine Chemistry

Volumn 121, Issue 2, 2003, Pages 223-225

  Lermontov, Sergei A ^a   Shkavrov, Sergei V ^a   Kuryleva, Nina V ^a  

^a INSTITUTE OF PHYSIOLOGICALLY ACTIVE COMPOUNDS   (Russian Federation)

Author keywords

Hexafluoroacetone; Hexafluoroisopropanol; High temperature alcohols; Meerwein Ponndorf Verley (MPV) reduction; Methyl trifluoropyruvate; Trifluorolactic esters

Indexed keywords

ALCOHOL DERIVATIVE; CARBONYL DERIVATIVE; ESTER DERIVATIVE; HEXAFLUOROACETONE; ORGANOFLUORINE DERIVATIVE; PYRUVIC ACID DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CONTROLLED STUDY; FLUORINATION; HIGH TEMPERATURE; HYDROLYSIS; METHYLATION; REDUCTION KINETICS; TRANSESTERIFICATION;

EID: 0038329185     PISSN: 00221139     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-1139(03)00036-8     Document Type: Article

References (12)

1. de Graauw, C.F. Peters, J.A. van Bekkum, H. Huskens, J. Synthesis (1994) 1007-1017.
2. Campbell E.J.Zhou H.Nguyen S.T. Org. Lett. 3 2001 2391-2393.
3. K. Konishi, M. Kazuyuki, T. Aida, S. Inoue, J. Chem. Soc., Chem. Commun. (1988) 643-645.
4. Ooi T.Miura T.Maruoka K. Angew. Chem. Int. Ed. Engl. 37 1998 2347-2349.
5. P.S. Kumbhar, J. Sanchez-Valente, J. Lopez, F. Figneras, J. Chem. Soc., Chem. Commun. (1998) 535-536.
6. Kaspar J.Trovarelly A.Lenarda M.Graziani M. Tetrahedron Lett. 30 1989 2705-2706.
7. Creyghton E.J.Ganeshie S.D.Downing R.S.van Bekkum H. J. Mol. Catal. A Chem. 115 1997 457-472.
8. Bagnell, L. Strauss, C.R. J. Chem. Soc., Chem. Commun. (1999) 287-288.
9. B.M. Regan, US Patent 3,702,872 (1972).
10. Katagiri, T. Obara, F. Toda, S. Furuhashi, K. Synlett. (1994) 507-508.
11. Bussche-Hunnefeld C.Cescato C.Seebach D. Chem. Ber. 125 1992 2795-2802.
12. Gambaryan N.P.Rokhlin E.M.Zeifman Yu.V.Ching-Yun C.Knunyants I.L. Angew. Chem. 78 1966 1008-1017.