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Volumn 5, Issue 8, 2003, Pages 1229-1231

Successive iodine-magnesium or -copper exchange reactions for the selective functionalization of polyhalogenated aromatics

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUND; BENZENE DERIVATIVE; BENZOIC ACID DERIVATIVE; CHELATING AGENT; COPPER; HALOGEN; IODINE; MAGNESIUM;

EID: 0038307293     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0341492     Document Type: Article
Times cited : (49)

References (22)
  • 14
    • 0141437707 scopus 로고    scopus 로고
    • note
    • 2,3,5-Triiodobenzoic acid is commercially available from Aldrich.
  • 18
    • 0141549272 scopus 로고    scopus 로고
    • note
    • 4, and concentrated in vacuo. Purification by flash chromatography (n-pentane/diethyl ether = 10:1) yielded 310 mg (70% yield) of 4e as a white solid, mp 76°C.
  • 20
    • 0012397313 scopus 로고
    • This effect has been extensively used to perform ortho-directed metalations: Snieckus, V. Chem. Rev. 1990, 90, 879.
    • (1990) Chem. Rev. , vol.90 , pp. 879
    • Snieckus, V.1
  • 22
    • 0141437706 scopus 로고    scopus 로고
    • note
    • 4, and concentrated in vacuo. Purification by flash chromatography (n-pentane/diethyl ether = 2:1) yielded 295 mg (70%) of 6g as a colorless oil.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.