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Volumn 118, Issue 20, 2003, Pages 9233-9240

Rydberg-valence interactions in CH2Cl→CH2+Cl photodissociation: Dependence of absorption probability on ground state vibrational excitation

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; CARRIER CONCENTRATION; CHLORINE COMPOUNDS; ELECTRONIC STRUCTURE; GROUND STATE; MOLECULAR VIBRATIONS; PHOTODISSOCIATION; PROBABILITY;

EID: 0038278527     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1568076     Document Type: Article
Times cited : (13)

References (43)
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    • (1995) Advances in Photochemistry , vol.20 , pp. 79-163
    • Francisco, J.S.1    Maricq, M.M.2
  • 3
    • 0004188481 scopus 로고
    • Cambridge Monographs on Atomic, Molecular, and Chemical Physics (Cambridge University Press, Cambridge)
    • R. Schinke, Photodissociation Dynamics, Cambridge Monographs on Atomic, Molecular, and Chemical Physics (Cambridge University Press, Cambridge, 1993).
    • (1993) Photodissociation Dynamics
    • Schinke, R.1
  • 9
    • 0017316527 scopus 로고
    • L. Salem, Science 191, 822 (1976).
    • (1976) Science , vol.191 , pp. 822
    • Salem, L.1
  • 14
    • 0038085114 scopus 로고    scopus 로고
    • NIST Chemistry Webbook
    • NIST Chemistry Webbook, webbook.nist.gov/chemistry/
  • 26
    • 0004040379 scopus 로고
    • Note
    • J.F. Stanton, J. Gauss, J.D. Watts, W.J. Lauderdale, and R.J. Bartlett, ACES II, 1993. The package also contains modified versions of the Molecule Gaussian integral program of J. Almlöf and P.R. Taylor, the ABACUS integral derivative program written by T.U. Helgaker, H.J.Aa. Jensen, P. Jørgensen, and P.R. Taylor, and the PROPS property evaluation integral code of P.R. Taylor.
    • (1993) ACES II
    • Stanton, J.F.1    Gauss, J.2    Watts, J.D.3    Lauderdale, W.J.4    Bartlett, R.J.5
  • 34
    • 0038423769 scopus 로고    scopus 로고
    • note
    • 1 Rydberg state by using the EOM-CCSD method, however, because of the strong coupling between this state and the valence state we were unable to locate the equilibrium structure of the Rydberg state on the multidimensional PES.
  • 35
    • 0038423768 scopus 로고
    • Excited states of saturated molecules
    • edited by B. Pullman and N. Goldblum (Reidel, Dordrecht, Holland)
    • M.S. Gordon and J.W. Caldwell, "Excited states of saturated molecules," in Excited States in Organic Chemistry and Biochemistry, edited by B. Pullman and N. Goldblum (Reidel, Dordrecht, Holland, 1977), pp. 257-270.
    • (1977) Excited States in Organic Chemistry and Biochemistry , pp. 257-270
    • Gordon, M.S.1    Caldwell, J.W.2
  • 42
    • 0038085110 scopus 로고    scopus 로고
    • note
    • 2> separately one can characterize the deviation of the electron distribution from a spherical shape. For s-type Rydberg states this deviation is expected to be small, while p-type Rydberg states will exhibit larger charge anisotropy.


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