Stereochemistry and Kinetic Deuterium Isotope Effects in the Thermal 1,3-Sigmatropic Rearrangement of (−)-(R,R)-trans-2-Methyl-1 -(1-tert-butylvinyl)cycIopropane: Evidence for a Biradical Intermediate

Journal of the American Chemical Society

Volumn 106, Issue 3, 1984, Pages 802-803

  Gajewski, Joseph J ^a   Warner, James Michael ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0038276401     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00315a063     Document Type: Article

References (13)

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3. Gajewski, J. J. “Hydrocarbon Thermal Isomerizations”; Academic Press: New York, 1981.
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5. 1972, 94, 3946.
6. Gajewski, J. J.; Benner, C. W.; Stahly, B. N.; Hall, R. F.; Sato, R. I. Tetrahedron 1982, 38, 853.
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13. Klärner, F.-G.; Brassel, B. J. Am. Chem. Soc. 1980, 102, 2469.